POSITIVE ELECTRODE MATERIALS FOR HIGH DISCHARGE CAPACITY LITHIUM ION BATTERIES

摘要

Positive electrode active materials are described that have a high tap density and high specific discharge capacity upon cycling at room temperature and at a moderate discharge rate. Some materials of interest have the formula Li_1+xNi_αMn_βCo_γO₂, where x ranges from about 0.05 to about 0.25, α ranges from about 0.1 to about 0.4, β ranges from about 0.4 to about 0.65, and γ ranges from about 0.05 to about 0.3. The materials can be coated with a metal fluoride to improve the performance of the materials especially upon cycling. Also, the coated materials can exhibit a very significant decrease in the irreversible capacity lose upon the first charge and discharge of the battery.