SYNTHESIS OF GLUCOSIDES RELATED TO GRAPE AND WINE AROMA PRECURSORS

摘要

Syntheses of the following glucosides are reported: 3',5',5'-trimethyl-3'-cyclohexenyl beta-D-glucopyranoside, 3'-(1 ''-cyclohexenyl)-1'-methyl-2'-propynyl-beta-D-glucopyranoside, (3'R*,9'S*)-3'-hydroxy-5'-megastigmen-7'-yn-9'-yl beta-D-glucopyranoside, (E,3'R*)-7'-oxo-5',8'-megastigmadien-3'-yl beta-D-glucopyranoside, and 4'-oxo-5'-megastigmen-9'-yl beta-D-glucopyranoside.