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Changes of Antioxidant Activity in Honey as a Result of Haber-Wais Reaction

机译:Haber-Wais反应导致蜂蜜中抗氧化活性的变化

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The antioxidants present in natural food products show a higher antioxidant activity than synthetic one [1]. Polyphenolic compounds are the most important antioxidants in bee honey. In addition to the polyphenols there are non-phenolic compounds with antioxidant potential, such as proteins, gluconic acid, L-ascorbic acid, hydrogen peroxide, hydroxyl methyl furfural (HMF), Maillard reaction products, etc. The antioxidant activity of honey largely depends on the content of micro biogenic elements. Cu acts as antioxidant because it is an integral part of some enzymes involved in the antioxidant activity of the organism. Cu in honey also acts as a pro-oxidant through Haber-weis reaction with L-ascorbic acid also present in honey. In addition to being an essential micro-nutrient Cu is potentially very hazardous because of the capacity change in oxidation state leading to the initiation of the reaction in which free radicals are formed. Therefore, the balanced intake of copper and other trace elements in the human body is very important. Therefore, changes in the antioxidant activity of food are the result of chemical changes in antioxidant active compounds present in the food product.
机译:天然食品中存在的抗氧化剂显示出比合成食品更高的抗氧化剂活性[1]。多酚类化合物是蜂蜂蜜中最重要的抗氧化剂。除多酚外,还有具有抗氧化作用的非酚类化合物,例如蛋白质,葡萄糖酸,L-抗坏血酸,过氧化氢,羟甲基糠醛(HMF),美拉德反应产物等。蜂蜜的抗氧化活性在很大程度上取决于微量生物成因元素的含量。铜起抗氧化剂的作用,因为它是与生物体的抗氧化活性有关的某些酶的组成部分。蜂蜜中的铜还通过与蜂蜜中也存在的L-抗坏血酸发生Haber-weis反应而作为前氧化剂。除了作为必需的微量营养元素外,Cu还可能非常危险,因为氧化态的容量变化会导致引发自由基的反应开始。因此,均衡摄取人体中的铜和其他微量元素非常重要。因此,食品抗氧化活性的变化是食品中存在的抗氧化活性化合物发生化学变化的结果。

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