Physicochemical Properties of Phosphate Ester from Palm Kernel Oil

摘要

The physicochemical properties of phosphate ester from palm kernel oil have been studied. The phosphate ester was synthesized via ring-opening of epoxidized palm kernel oil with phosphoric acid. The amount of phosphoric acid (H_3PO_4) was varied at 0, 2.5, 5.0 and 7.5 wt%. Acid values of PKO and EPKO were 1.85 and 1.87 mg KOH/g respectively. However, the acid values increased with increasing amount of H_3PO_4 with values of 10.62 mg KOH/g,31.34 mg KOH/g and 110.95 mg KOH/g respectively. The hydrolysis of the EPKO has successfully converted it to PEPKO with hydroxyl value of 16.16 mg KOH/g, 26.90 and 35.33 mg KOH/g at H_3PO_4 of 2.5, 5.0, and 7.5wt%.