首页> 外国专利> Process for preparing substituted aromatic amines.

Process for preparing substituted aromatic amines.

机译:制备取代的芳族胺的方法。

摘要

There is provided a process for preparing azo compounds substituted aromatic CONSISTING contacting a nucleophilic compound and azo containing compound in the presence of suitable solvent system, and reacting the nucleophilic compound and azo containing compound in the presence of base ACCEPTABLE QUANTITY AND CONTROLLED protic material at a temperature of about 10 (degrees) CA aPPROXIMATELY 150 (DEGREES) C IN CONFINED a reaction zone wherein the molar ratio of protic material BASED is 0: 1 to about 5: 1. In another embodiment, azo compounds substituted aromatic REACT IN ADDITION with a nucleophilic compound in the presence of a solvent suitable system, an appropriate base and a controlled amount of protic material at a temperature of about 70 (degrees) CA APPROXIMATELY 200 (degrees) C EN a reaction zone chamber into which the molar ratio of protic material to BASE is 0: 1 to about 5: 1 to produce an aromatic amine REPLACED. In another embodiment, there is provided a process for PREPARES aromatic amines REPLACED CONSISTING contacting a nucleophilic compound and azo compound substituted aromatic presence of a suitable solvent system, and reacting the nucleophilic compound and the AZO AROMATICO REPLACED IN THE PRESENCE OF PROPER base and a controlled amount of protic material at a temperature of about 70 (degrees) CA aPPROXIMATELY 200 (degrees) C in a reaction zone chamber into which the molar ratio of protic A base material is 0: 1 to about 5 1 E another embodiment, substituted aromatic amines THE iNVENTION RENT TO PRODUCE reductively alkylated diamines or substituted derivatives thereof.
机译:提供了一种制备取代的芳族化合物的偶氮化合物的方法,该方法包括在合适的溶剂体系存在下使亲核化合物和含偶氮化合物接触,并使亲核化合物和含偶氮化合物在碱可接受的量和受控质子材料存在下于室温下反应。大约10(度)的温度,大约150(度)的温度限制在一个反应​​区中,其中质子材料BASED的摩尔比为0:1到大约5:1。在另一个实施方案中,偶氮化合物用A取代芳族反应。亲核化合物,在合适的溶剂体系,合适的碱和受控量的质子传递材料(温度约为70(度))的条件下进行。CA大约200(度)C EN反应区室,质子传递材料的摩尔比进入与BASE的比率为0:1至约5:1以产生芳族胺REPLACED。在另一个实施方案中,提供了一种制备PREPARES芳族胺的方法,该方法是使亲核化合物和偶氮化合物取代的芳族化合物在合适的溶剂体系中接触,并使亲核化合物和偶氮芳族芳香族化合物置换为存在适当碱和可控溶剂的情况。在质子A基体材料的摩尔比为0:1至约5 1 E的反应区室中,在约70(度)的温度下约200(度)的质子传递材料的量。另一个实施方案,取代的芳族胺本发明旨在生产还原性烷基化的二胺或其取代的衍生物。

著录项

  • 公开/公告号ES2099440T3

    专利类型

  • 公开/公告日1997-05-16

    原文格式PDF

  • 申请/专利权人 MONSANTO COMPANY;

    申请/专利号ES19930911630T

  • 发明设计人 STERN MICHAEL KEITH;CHENG BRIAN KAI-MING;

    申请日1993-04-13

  • 分类号C07C245/08;C07C209/02;C07C209/42;C07C209/54;

  • 国家 ES

  • 入库时间 2022-08-22 03:23:59

相似文献

  • 专利
  • 外文文献
  • 中文文献
获取专利

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号