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Synthesis of new heterocycles through the reaction of beta-lapachone with 1,2-diamines using Triton X-100 surfactant as catalyst in aqueous medium

机译:在水性介质中使用Triton X-100表面活性剂与1,2-二胺的β-乙酰酮的反应合成新的杂环

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摘要

An efficient and an environmentally benign protocol has been developed for the synthesis of new naphtha-azaquinoxaline and naphtha-benzoquinoxaline derivatives from the reaction of beta-lapachone, a naturally occurring 1,2-naphthoquinone with various 1,2-diamines using surfactant as catalyst in aqueous medium. This method has advantage of easy handling and good yield of products in shorter time. The structures were assigned with the help of analytical and H-1, C-13 NMR, IR, and mass spectral studies.
机译:已经开发了一种高效和环境良性方案,用于合成新的石脑油 - 氮杂喹喔啉和石脑油 - 苯喹喔啉衍生物,从β-乙酰酮的反应,天然存在的1,2-萘醌,使用表面活性剂作为催化剂 在水性介质中。 这种方法在较短的时间内具有易于处理和良好的产品收益率。 借助分析和H-1,C-13 NMR,IR和质谱研究分配了结构。

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