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Multilayer structure, stress reduction and annealing of carbon film

机译:多层结构,应力降低和碳膜退火

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Carbon films deposited by filtered cathodic arc show a high compressive stress which limits their thickness because of delamination. We study three methods of relieving the stress in these films. We first determine the dependence of the stress on DC bias up to bias voltages of 1200V and show that the formula of Davis provides a good fit to tlie data including the stress maximum in the region of 150-200V and the progressive decrease in stress at higher voltages. In the second method, plasma immersion ion implantation (PHI) was used to create multilayer of alternating high density, high stress (PHI on) films and lower density, low stress (PHI off) films. This method enabled thicker structures to be produced. In the third method we made multilayers using amorphous silicon and carbon layers. Annealing of these layers showed that the stress could be reduced to very low values because of the ability of the silicon layers to absorb compressive stress by contracting after tlie annealing step. The microstructural effects of PHI were studied by transmission and scanning electron microscopy.
机译:过滤的阴极弧沉积的碳膜显示出高压缩应力,其限制了它们由于分层而限制它们的厚度。我们研究了三种缓解这些薄膜压力的方法。我们首先确定压力对直流偏置的依赖性,直到1200V的偏置电压,并表明戴维斯的公式为TLIE数据提供了良好的数据,包括150-200V区域中的应力,并且较高压力的逐步降低电压。在第二种方法中,使用等离子体浸渍离子注入(PHI)来产生多层交替的高密度,高应力(PHI)膜和更低的密度,低应力(PHI OFF)膜。该方法使能较厚的结构产生。在第三种方法中,我们使用非晶硅和碳层制造多层。这些层的退火表明,由于硅层通过在TLIE退火步骤之后通过收缩而吸收压缩应力的能力,应力降低到非常低的值。通过透射和扫描电子显微镜研究了PHI的微观结构效应。

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