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Lead-free solder alloy, solder ball and electronic member, and lead-free solder alloy, solder ball and electronic member for automobile-mounted electronic member
Lead-free solder alloy, solder ball and electronic member, and lead-free solder alloy, solder ball and electronic member for automobile-mounted electronic member
A lead-free solder alloy exhibiting good performance in impact resistance and vibration resistance. Also provided are a solder ball using such a lead-free solder alloy, and an electronic member having a solder bump using such a lead-free alloy. Specifically, the lead-free solder alloy consists of 1.0 to 2.0% by mass of Ag, 0.3 to 1.0% by mass of Cu, 0.005 to 0.1% by mass of Ni and the balance including Sn and unavoidable impurities. In an Sn—Ag—Cu based solder joint portion on a Cu electrode, a Cu3Sn intermetallic compound layer is formed directly on the Cu electrode, and then a Cu6Sn5 intermetallic compound layer is formed thereon. A Cu atomic site in the Cu6Sn5 intermetallic compound layer is replaced by Ni having a smaller atomic radius than Cu to thereby reduce strain in the Cu6Sn5 intermetallic compound layer, thus enabling impact resistance and vibration resistance to be improved therein.
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机译:无铅焊料合金在抗冲击性和抗振性方面表现出良好的性能。还提供了使用这种无铅焊料合金的焊球,以及使用这种无铅合金的具有焊料凸点的电子部件。具体地,无铅焊料合金由1.0至2.0质量%的Ag,0.3至1.0质量%的Cu,0.005至0.1质量%的Ni以及余量包括Sn和不可避免的杂质组成。在Cu电极上的Sn-Ag-Cu基焊点部分中,直接在Cu电极上形成Cu 3 Sub> Sn金属间化合物层,然后形成Cu 6 Sub>在其上形成Sn 5 Sub>金属间化合物层。 Cu 6 Sub> Sn 5 Sub>金属间化合物层中的Cu原子位点被原子半径小于Cu的Ni取代,从而降低了Cu 6 < / Sub> Sn 5 Sub>金属间化合物层,因此可以改善其中的抗冲击性和抗振性。
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