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Polyamide-containing monomeric units of 1,4-butylene diamine

机译:1,4-丁二胺的含聚酰胺单体单元

摘要

A method for producing a polyamide containing a monomer unit of diamines derived therefrom and / or dicarboxylic acids of the fatty acid-based as well as aliphatic dicarboxylic acids having carbon atoms to 12 or 1,4-butylene diamine, 6, a 50% by weight an aqueous salt mixture containing a diamine derived therefrom and / or dicarboxylic acids of the fatty acid-based as well as aliphatic dicarboxylic acids having carbon atoms to 12 atoms) 1,4-butylene diamine, 6 step of distilling the mixture until the water less than 15% by weight at a pressure of 16barg below while maintained at a temperature high enough to produce a mixture containing water, to be left in the liquid that the mixture and a step of starting by increasing to up to 180 ℃ at least the temperature, the polymerization of the mixture obtained in step a) b) the reactive group of 80% before it is converted at least in c) required The method includes the step of supplying the reaction mixture diamine derived therefrom and / or dicarboxylic acids of the fatty acid-based as well as aliphatic dicarboxylic acids, depending, carbon atoms to 12 or more 1,4-butylene diamine, 6 . The present invention also relates to the shaped articles obtained polyamide compositions comprising a polyamide and its made from the composition.
机译:一种生产聚酰胺的方法,该聚酰胺含有由其衍生的二胺和/或基于脂肪酸的二羧酸的单体单元,以及具有碳原子为12或1,4-丁二胺的脂肪族二羧酸,6、50%称重的水盐混合物,其中包含由其衍生的二胺和/或基于脂肪酸的二羧酸以及具有碳原子至12个原子的脂肪族二羧酸)1,4-丁烯二胺,将混合物蒸馏至水的6个步骤在低于16barg的压力下小于15%的重量,同时保持在足以产生含水混合物的温度下,要留在液体中,使混合物和至少从180℃开始加热的步骤温度下,步骤a)中获得的混合物的聚合反应b)至少在c)中转化之前80%的反应性基团。该方法包括提供由其衍生的反应混合物二胺和/或d的步骤脂肪酸基脂肪族二羧酸和脂肪族二羧酸,取决于12或更多的1,4-丁二胺6的碳原子。本发明还涉及由聚酰胺制成的成形制品,所述聚酰胺组合物包含聚酰胺及其由所述组合物制成。

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