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Anisotropic dewetting in ultra-thin single-crystal silicon-on-insulator films

机译:超薄单晶硅绝缘体薄膜中的各向异性去湿

摘要

The single crystal silicon-on-insulator thin film materials system represents both an ideal model system for the study of anisotropic thin film dewetting as well as a technologically important system for the development of the next generation of MOSFET devices. The scientific community has misinterpreted the mechanism behind SOI dewetting, attributing it to a stress-driven instability. In this work, we characterize and measure the kinetics and geometry of thermally-activated dewetting in ultra-thin SOI films as a function of SOI thickness, crystallographic patterned-edge orientation, and temperature. Using experimental data and physical reasoning, we strongly argue against the previously existing scientific consensus that SOI dewetting is a stress-driven instability and present a 5-step isotropic surface-energy-driven dewetting model based upon the capillary film edge instability and the generalized Rayleigh instability, in which we integrate existing theories and in addition develop an expression for the edge retraction distance during the initial uniform edge thickening and retraction phase of dewetting at a patterned mesa edge for the first time, predicting a square root dependence with time and an inverse power dependence on film thickness. In our study, we observe and quantify the kinetics of the initial edge retraction dewetting mechanism experimentally for the first time and confirm the square root time dependence and inverse power law film thickness dependence predicted by our new model. We also quantify the edge dewetting front propagation velocity in SOI and determine that it depends on the negative third power of the film thickness, agreeing with the prediction of Jiran and Thompson and with our model.
机译:绝缘体上单晶硅薄膜材料系统既是研究各向异性薄膜去湿的理想模型系统,又是开发下一代MOSFET器件的技术上重要的系统。科学界误解了SOI去湿的机制,将其归因于压力驱动的不稳定。在这项工作中,我们表征并测量了超薄SOI膜中热活化去湿的动力学和几何形状,其与SOI厚度,晶体学图案化边缘取向和温度有关。使用实验数据和物理推理,我们强烈反对先前存在的科学共识,即SOI去湿是应力驱动的不稳定性,并基于毛细管膜边缘不稳定性和广义Rayleigh提出了五步各向同性表面能驱动的去湿模型不稳定性,其中我们结合了现有理论,此外还开发了一种表达式,用于首次在图案化的台面边缘进行去湿的初始均匀边缘增厚和缩回阶段期间的边缘缩回距离,从而预测随时间的平方根依赖性和反函数功率取决于薄膜厚度。在我们的研究中,我们首次通过实验观察和量化了初始边缘回缩去湿机理的动力学,并确认了我们的新模型预测的平方根时间依赖性和逆幂律膜厚度依赖性。我们还量化了SOI中的边缘去湿前沿传播速度,并确定它取决于膜厚的负三次方,与Jiran和Thompson的预测以及我们的模型一致。

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