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Research Brief: Applying Green Chemistry Principles Towards the Sustainable Synthesis of Biodiesel from Waste Vegetable Oil

机译:研究摘要:将绿色化学原理应用于植物油废料可持续合成生物柴油

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摘要

In 2011, the U.S. consumed over 18 million barrels per day of refined petroleum products and biofuels; almost 22% of global petroleum consumption. This includes oil used for transportation, electricity, and production of consumer products. More than half of this oil was imported from foreign countries, and in his 2006 State of the Union Address President Bush warned that, “We have a serious problem, America is addicted to oil, which is often imported from unstable parts of the world”. With the need for new energy sources more apparent than ever, serious research is needed to further the advancement of alternative fuels, so that they may become a more practical source of energy. Biodiesel is an alternative fuel to petroleum diesel, and is produced from renewable and/or recycled resources. Biodiesel’s benefits include reduced emissions of unburned hydrocarbons, carbon monoxide, particulate matter and nitrogen oxides, plus reduction of greenhouse gas emissions. The process of making biodiesel involves transesterification of triacyl-glycerides in Waste Vegetable Oil (WVO) with methanol, using potassium hydroxide (KOH) as a catalyst.Research in Dr. Brush’s group has focused on developing an efficient and cost-effective process for converting 50 liter (13 gallon) batches of Waste Vegetable Oil (WVO) from BSU cafeterias into biodiesel fuel for campus use. However, in a detailed analysis of our efficiency in producing biodiesel by this traditional process, we found that this “simple” transesterification reaction is only one small part of a complex, interrelated, and inefficient overall production process.
机译:2011年,美国每天消耗超过1800万桶的精炼石油产品和生物燃料;占全球石油消费量的近22%。这包括用于运输,电力和消费品生产的石油。这种石油有一半以上是从国外进口的,布什总统在2006年的国情咨文中警告说:“我们有一个严重的问题,美国沉迷于石油,而石油通常是从世界不稳定地区进口的” 。随着对新能源的需求比以往更加明显,需要认真研究以进一步发展替代燃料,以使它们可以成为更实用的能源。生物柴油是石油柴油的替代燃料,由可再生和/或循环利用资源生产。生物柴油的好处包括减少未燃烧的碳氢化合物,一氧化碳,颗粒物和氮氧化物的排放,以及减少温室气体的排放。生物柴油的生产过程涉及废植物油(WVO)中的三酰基甘油酯与甲醇的酯交换反应,使用氢氧化钾(KOH)作为催化剂。Brush博士小组的研究重点是开发一种高效且经济高效的转化方法来自BSU自助餐厅的50升(13加仑)批次的废植物油(WVO)转化为生物柴油供校园使用。但是,在对我们通过这种传统方法生产生物柴油的效率进行的详细分析中,我们发现这种“简单”的酯交换反应只是复杂,相互关联且效率低下的整个生产过程的一小部分。

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    Ackley Brandon;

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