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Kinetic Analysis and Optimization of Long Chain Branched Propylene Polymerization System

机译:长链支化丙烯聚合体系的动力学分析和优化

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摘要

A kinetic model has been proposed for a binary catalyst system with the available experimentaluddata from the open literature, in which one catalyst produces polypropylene macromonomer, while theudother catalyst attacks the macromonomers as side chains to the isotactic polypropylene backbone. Afterudvalidating the model with the experimental data, it has been extended to find the optimal processudconditions for the desired combination of conflicting objectives that leads to manufacturing of polymerudwith controlled branching suitable for varied kind of applications. A well-established multi-objectiveudoptimization technique, NSGA II, has been utilized for this purpose. Some of the Pareto optimal points areudfound to be better than the experimental data and show improvement in process performance.
机译:已经提出了具有公开文献中可用的实验数据的二元催化剂体系的动力学模型,其中一种催化剂产生聚丙烯大分子单体,而另一种催化剂攻击大分子单体作为到全同立构聚丙烯主链的侧链。用实验数据对模型进行验证后,已进行了扩展,以找到针对冲突目标的理想组合的最佳过程/条件,从而导致制造聚合物/控制支链适用于各种类型的应用。为此目的,使用了一种完善的多目标非优化技术NSGA II。某些帕累托最优点被发现优于实验数据,并显示出工艺性能的提高。

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