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Silica Anchored Bis(Trialkylphosphine) Platinum Oxalate. A Photogenerated Catalyst for Olefin Hydrosilation

机译：二氧化硅锚定双（三烷基膦）铂草酸盐。用于烯烃硅氢化的光生催化剂

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摘要

Ultraviolet irradiation of the silica attached complex Pt(C2O4)L2, L = (H3CO)3-Si(Ch2)2PEt2, yields a SiO2-L2Pt species that catalyze olefin hydrosilation or adds 2 CO to yield a surface dicarbonyl complex.

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Prignano, A. L.; Trogler, W. C.;
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年度 1986
页码 p.1-4
总页数 4
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Catalysts; Synthesis(Chemistry); Oxalates; Platinum compounds; Phosphine; Silicon dioxide; Photolysis; Ultraviolet radiation; Catalysis; Hydration; Ligands; Reprints;

机译：催化剂;合成（化学）;草酸盐;铂化合物;膦;二氧化硅;光解;紫外线;催化;水合;配体;重印;

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专利

1. PLATINUM(II) BIS(BETA-DIKETONATES) AS PHOTOACTIVATED HYDROSILATION CATALYSTS [J] . Lewis FD., Salvi GD. Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1995,第12期

机译：铂（II）双（双-丁酮酸酯）作为光活化水合催化剂
2. From homogeneous to heterogeneous catalysis: Novel anchoring of polypyrazolylborate copper(I) complexes on silica gel through classical and nonclassical hydrogen bonds. Use as catalysts of the olefin cyclopropanation reaction [J] . Diaz-Requejo MM., Nicasio MC., Perez PJ., Organometallics . 2000,第3期

机译：从均相催化到异相催化：通过经典和非经典氢键将聚吡唑硼酸铜（I）络合物在硅胶上的新型锚固。用作烯烃环丙烷化反应的催化剂
3. Molecular manganese catalyst anchored on Bi_2MoO_6 with enhanced photogenerated charges separation for efficient visible-light photoreduction of CO_2 [J] . Zhang Lu, Wang Wei, Wang Hui, Journal of materials science . 2019,第6期

机译：分子锰催化剂固定在Bi_2MoO_6上，具有增强的光生电荷分离能力，可有效地将CO_2可见光还原
4. Bis(benzimidazole)amine Vanadium Catalysts for Olefin Polymerization and Copolymerization:Thermally Robust, Single-Site Catalysts Activated by Simple Alkylaluminum Reagents [C] . Atanas K. Tomov, Vernon C. Gibson, Damien Zaher Division of Polymeric Material: Science and Engineering American Chemical Society meeting . 2004

机译：BIS（苯并咪唑）胺钒催化剂用于烯烃聚合和共聚：通过简单的烷基铝试剂激活的热稳健，单现场催化剂
5. Adamantyl silica for RP-HPLC via olefin hydrosilation on a hydride intermediate. [D] . Tong, Susan. 1995

机译：通过在氢化物中间体上进行的烯烃硅氢化作用，用于RP-HPLC的金刚烷基二氧化硅
6. Efficient alkene hydrosilation with bis(8-quinolyl)phosphine (NPN) nickel catalysts. The dominant role of silyl-over hydrido-nickel catalytic intermediates [O] . Jian Yang, Verònica Postils, Michael I. Lipschutz, 2020

机译：用双（8-喹啉基）膦（NPN）镍催化剂的高效烯烃氢化。甲硅烷基于水合镍镍催化中间体的显性作用
7. I. Nickel-Exchanged Zincosilicate Catalysts for the Oligomerization of Propylene and II. Organic SDA-Free Catalysts for the Methanol-to-Olefins Reaction [O] . Deimund Mark Austin 2015

机译：I.镍交换的Zincosilicate催化剂用于丙烯和II的低聚反应。用于甲醇制烯烃反应的有机无sDa催化剂
8. Silica-Supported Bis(trialkylphosphine)platinum Oxalates. Photogenerated Catalysts for Hydrosilation of Olefins [R] . Prignano, A. L., Trogler, W. C. 1987

机译：二氧化硅负载的双（三烷基膦）铂草酸盐。用于烯烃硅氢化的光生催化剂

Silica Anchored Bis(Trialkylphosphine) Platinum Oxalate. A Photogenerated Catalyst for Olefin Hydrosilation

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