Structural studies of silica- and alumina-pinned nanocrystalline SnO_2

摘要

Sol-gel-prepared nanocrystalline tin (IV) oxide has been characterized by magic angle spinning nuclear magnetic resonance (MAS NMR) in a pure form and also with silica and alumina pinning phases present. The u9Sn MAS NMR lineshape was observed to broaden as the SnO_2 nanocrystal sizes decreased, a reflection of the increasingly important contribution of the more disordered surface region. A second local Sn environment other than the cassiterite phase was observed, probably an orthorhombic phase that has previously been observed in nanoparticles of SnO_2. The silica and alumina pinning particles were characterized by 29Si and 27 Al MAS NMR. The silica pinning particles retained a high degree of disorder over the range of annealing temperatures, whereas alumina crystallized at ~1000 deg C. A possible explanation for this difference is that since the alumina pinning particles are less successful at restricting nanocrystal growth than the silica particles, they may aggregate together and combine, hence they are larger, less constrained particles.