A thermodynamic derivative means an experiment

摘要

All too often. courses in thermodynamics and statistical mechanics barrage their students with numerous equations that are left unexamined and uninvestigated. This note explains how to pause, examine a thermodynamic equation, and render it more meaningful. Three techniques are discussed: (1) design two experiments that would measure the quantities on either side of the equality; (2) examine special cases; (3) consider the consequences if the equality failed to hold. (C) 1999 American Association of Physics Teachers. [References: 5]