Thermodynamic Properties of Organic Derivatives of the Lighter Elements and Thermodynamic Properties of Fluids.

摘要

An investigation of strained small-ring compounds in families of cyclic amines and epoxy butanes was continued. The thermodynamic properties of 1,2-epoxybutane including enthalpy of combustion and formation,low-temperature thermal properties,vapor pressures,enthalpy of vaporization,and the values of enthalpy,entropy,Gibbs energy,and equilibrium constant of formation in the vapor state at 298.15 K are completed;work on trans-2,3-epoxybutane is in progress;and the investigation of cyclopentylamine is about 90percent completed. (Author)