首页> 外文期刊>Journal of Physical Organic Chemistry >A natural bond orbital analysis of aryl‐substituted polyfluorinated carbanions: negative hyperconjugation

【24h】

A natural bond orbital analysis of aryl‐substituted polyfluorinated carbanions: negative hyperconjugation

机译：芳基取代的多氟碳酸碳酸盐的天然键分析：阴性高速凝固

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Abstract > Aryl‐substituted polyfluorinated carbanions, ArCHR <sub>f</sub> ? where R <sub>f</sub> ?=?CF <sub>3</sub> ( 1 ), C <sub>2</sub> F <sub>5</sub> ( 2 ), i ‐C <sub>3</sub> F <sub>7</sub> ( 3 ), and t ‐C <sub>4</sub> F <sub>9</sub> ( 4 ), were analyzed by means of the natural bond orbital (NBO) theory at the B3LYP/6‐311+G(d,p) computational level. A lone pair NBO at the formal anionic center carbon (Cα) was not found in the Lewis structure. Instead, significant donor/acceptor NBO interactions between π(Cα‐C1) and σ*(Cβ‐F) or σ*(Cβ‐Cγ) were observed for 1 , 2 , 3a (strong electron‐withdrawing substituent, from p ‐CF <sub>3</sub> to p ‐NO <sub>2</sub> ), and 4 . Their second‐order donor/acceptor perturbation interaction energy, E (2), values decreased with the increase of the stability of carbanions. A larger E (2) value corresponds to longer Cβ‐F and Cβ‐Cγ bonds and a shorter Cα‐Cβ bond, indicating that the E (2) values can be associated with the negative hyperconjugation of the Cβ‐F and Cβ‐Cγ bonds. In accordance with this, the E (2) values for π(Cα‐C1)?→?σ*(Cβ‐F) were linearly correlated with the Δ G o <sub>β‐F</sub> values (an empirical measure of β‐fluorine negative </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> >芳基取代的多氟菱形碳，Archr <sub> f </ sub> </ sup>其中r <sub> f </ sub>？=？cf <sub> 3 </ sub>（ 1 </ b>），c <sub> 2 </ sub> f <sub> 5 </ sub>（ 2 </ b>）， i </ i> -c <sub> 3 </ sum> f <sub> 7 </ sub>（ 3 </ b>）和 t </ i> -c <sub> 4 </ sub> f <sub> 9 </ sub>（ 4 </ b>），通过自然分析B3LYP / 6-311 + G（D，P）计算水平的键轨道（NBO）理论。在Lewis结构中未发现正式阴离子中心碳（Cα）的孤立对NBO。相反，对于π（Cα-C1）和σα（Cβ-F）或σα（Cβ-F）或σ*（Cβ-Cγ），对于 1， 2 </ b >， 3a </ b>（强电子 - 抽出取代基，从 p </ i> -cf <sub> 3 </ sub>至 p </ i> -no <sub> 2 </ sub>），和 4 </ b>。它们的二阶供体/受体扰动相互作用能量， e </ i>（2），随着碳气稳定性的增加而降低。较大的 e </ i>（2）值对应于较长的Cβ-F和Cβ-Cγ键和较短的Cα-Cβ键，表明 e </ i>（2）值可以是与Cβ-F和Cβ-Cγ键的阴性超强稳定相关。根据此，π（Cα-C1）α→σ*（Cβ-F）与δ为<β-/ i>线性相关的 e </ i>（2）值< sup> o </ sup> <sub>β-f </ sub>值（β-氟阴性的经验尺寸 </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-35546/'>《Journal of Physical Organic Chemistry》</a> <b style="margin: 0 2px;">|</b><span>2018年第1期</span><b style="margin: 0 2px;">|</b><span>共9页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Suenaga Masahiko&option=202" target="_blank" rel="nofollow">Suenaga Masahiko;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Nakata Kazuhide&option=202" target="_blank" rel="nofollow">Nakata Kazuhide;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Abboud José‐Luis M.&option=202" target="_blank" rel="nofollow">Abboud José‐Luis M.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Mishima Masaaki&option=202" target="_blank" rel="nofollow">Mishima Masaaki;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of Chemistry Graduate School of ScienceKyushu UniversityFukuoka Japan;</p> <p>Science Research CenterHosei UniversityTokyo Japan;</p> <p>Institute for Materials Chemistry and EngineeringKyushu UniversityFukuoka Japan;</p> <p>Institute for Materials Chemistry and EngineeringKyushu UniversityFukuoka Japan;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/4796.html" title="有机化学一般性问题">有机化学一般性问题;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=donor/acceptor NBO interaction energy&option=203" rel="nofollow">donor/acceptor NBO interaction energy;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=natural bond orbital analysis&option=203" rel="nofollow">natural bond orbital analysis;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=negative hyperconjugation&option=203" rel="nofollow">negative hyperconjugation;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=polyflourinated carbanions&option=203" rel="nofollow">polyflourinated carbanions;</a> </p> <div class="translation"> 机译：供体/受体NBO相互作用能量;天然键轨道分析;阴性超强凝固;多氟土; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704025793750.html">A natural bond orbital analysis of aryl‐substituted polyfluorinated carbanions: negative hyperconjugation</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Suenaga Masahiko&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Suenaga Masahiko,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Nakata Kazuhide&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Nakata Kazuhide,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Abboud José‐Luis M.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Abboud José‐Luis M.,</a> <a href="/journal-foreign-35546/" target="_blank" rel="nofollow" class="tuijian_authcolor">Journal of Physical Organic Chemistry .</a> <span>2018</span><span>,第1期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：芳基取代的多氟碳酸碳酸盐的天然键分析：阴性高速凝固</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704022247343.html">The role of hyperconjugation in the unusual conformation of thymine: A natural bond orbital analysis</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Rengifo Emerson&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Rengifo Emerson,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Gomez Sara&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Gomez Sara,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Arce Julio C.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Arce Julio C.,</a> <a href="/journal-foreign-16839/" target="_blank" rel="nofollow" class="tuijian_authcolor">Computational & theoretical chemistry .</a> <span>2018</span><span>,第期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：超强稳定在胸腺量不寻常构象中的作用：一种天然键轨道分析</span> </p> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/070401698184.html">A natural bond orbital analysis of carbanions</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Sauers R.R.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Sauers R.R. </a> <a href="/journal-foreign-16839/" target="_blank" rel="nofollow" class="tuijian_authcolor">Computational & theoretical chemistry .</a> <span>2012</span><span>,第Null期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：碳负离子的自然键轨道分析</span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-conference-foreign_meeting-286344_thesis/0705017227828.html">Natural Bond Orbital Analysis of creatinine: A DFT Approach Study</a> <b>[C]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Maheswata Moharana&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Maheswata Moharana,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Satya Narayan Sahu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Satya Narayan Sahu,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Subrat Kumar Pattanayak&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Subrat Kumar Pattanayak </a> <a href="/conference-foreign-286344/" target="_blank" rel="nofollow" class="tuijian_authcolor">International Conference on Advances in Basic Sciences .</a> <span>2019</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：肌酐天然键轨道分析：DFT方法研究</span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-degree-foreign_mphd_thesis/02061447521.html">Part I. Carbanion stabilization by adjacent sulfur: Polarizability, resonance, or negative hyperconjugation? Experimental distinction based on intrinsic rate constants from (phenylthio)nitromethane and 1-nitro-2-phenylethane. Part II. Mechanistic studies of hydrolysis and nucleophilic substitution of transition metal carbene complexes.</a> <b>[D] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Kittredge, Kevin Walter.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Kittredge, Kevin Walter. </a> <span>1998</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：第一部分：相邻硫磺对碳的稳定作用：极化率，共振或负超共轭？基于（苯硫基）硝基甲烷和1-硝基-2-苯基乙烷的固有速率常数进行实验区别。第二部分过渡金属卡宾配合物水解和亲核取代的机理研究。</span> </p> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-journal-foreign-pmc_detail_thesis/040007165131.html">Experimental and theoretical spectroscopic (FT-IR FT-Raman UV-VIS) analysis natural bonding orbitals and molecular docking studies on 2-bromo-6-methoxynaphthalene: A potential anti-cancer drug</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Rinnu Sara Saji&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Rinnu Sara Saji,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Johanan Christian Prasana&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Johanan Christian Prasana,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=S. Muthu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">S. Muthu,</a> <span>2021</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：实验和理论光谱（FT-IRFT-RamanUV-Vis）分析天然粘合轨道和2-溴-6-甲氧基萘的分子对接研究：潜在的抗癌药物</span> </p> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/open-access_resources_thesis/01000131976916.html">Conjugation and Hyperconjugation Effects: Comparative Studies Through Localized Molecular Orbitals Energy Decomposition Analysis (LMO-EDA) and Natural Bond Orbitals (NBO)</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=V. A. V. Ferreira&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">V. A. V. Ferreira,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=V. G. do Nascimento&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">V. G. do Nascimento,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=M. B. de Amorim&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">M. B. de Amorim </a> <span>2015</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：共轭和超功分效应：通过局部分子轨道能量分解分析（LMO-EDA）和天然键（NBO）的比较研究</span> </p> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chemical-journal-chinese-universities_thesis/0201290840693.html">Na2CO3催化的叠氮三甲基硅烷对δ-三氟甲基-δ-芳基取代对亚甲基苯醌的1,6-共轭加成:高效构建含三氟甲基和叠氮取代的二芳基甲烷化合物</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘华铮&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 刘华铮</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=潘小光&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,潘小光</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李华&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,李华</a> <span> <a href="/journal-cn-10958/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 高等学校化学学报 </a> </span> <span> . 2021</span><span>,第009期</span> </span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-cn_computing-techniques-geophysical-geochemical-exploration_thesis/0201254290890.html">碳酸盐矿物和碳酸盐岩天然热释光的实验研究</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=达雪娟&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 达雪娟</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=高柏原&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,高柏原</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=伊海生&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,伊海生</a> <span> <a href="/journal-cn-5023/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 物探化探计算技术 </a> </span> <span> . 2009</span><span>,第001期</span> </span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-cn_guangdong-chemical-industry_thesis/0201246337713.html">铱催化芳基C-H键硼化反应合成硼酸酯聚三氟苯乙烯</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=徐志安&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 徐志安</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=黄焰根&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,黄焰根</a> <span> <a href="/journal-cn-9122/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 广东化工 </a> </span> <span> . 2015</span><span>,第004期</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-journal-cn_detail_thesis/0201296146656.html">芳基胍碳酸盐的合成及抗菌活性初步研究</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=赵海&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 赵海</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=史海波&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,史海波</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=卢孔秦&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,卢孔秦</a> <span> <a href="/journal-cn-57282/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 精细化工中间体 </a> </span> <span> . 2012</span><span>,第6期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chemical-journal-chinese-universities_thesis/0201231560291.html">N-4-氯-2-取代氨基甲酰基-6-甲基苯基-1-芳基-5-氯-3-三氟甲基-1H-吡唑-4-甲酰胺的合成及生物活性</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=张秀兰&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 张秀兰</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王宝雷&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,王宝雷</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=毛明珍&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,毛明珍</a> <span> <a href="/journal-cn-10958/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 高等学校化学学报 </a> </span> <span> . 2013</span><span>,第001期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-22733_thesis/02022695827.html">三种1,2-二-β-(α-甲基-α'苯基)噻吩六氟环戊烯的苯基对位取代物红外光谱、核磁共振氢谱测定及碳氟键伸缩振动变化的研究</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=蒋凤池&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 蒋凤池</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘华卿&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,刘华卿</a> <span> <a href="/conference-cn-22733/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 第十四届全国分子光谱学学术会议 </a> <span> <span> . 2006</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/02031584889.html">碳酸银和二芳基碘盐促进的2,4-二取代-(4H)-5-噁唑酮芳基化反应的研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王彪&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 王彪</a> <span> . 2014</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120105123051.html">作为抗糖尿病药的α－(三氟甲基－取代的芳氧基、芳基氨基、芳硫基或芳基甲基)－三氟甲基－取代的苯乙酸和衍生物</a> <b>[P]</b> . <span> 中国专利： CN1922143A </span> <span> . 2007-02-28</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120104366034.html">氟取代的环状碳酸酯以及含有该氟取代环状碳酸酯的电解液和电池</a> <b>[P]</b> . <span> 中国专利： CN1161036A </span> <span> . 1997-10-01</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130409623401.html">Substituted 6-aryl-imidazopyridine and 6-aryl-triazolopyridine carboxamide analogs as negative allosteric modulators of mGluR5</a> <b>[P]</b> . <span> 外国专利：  US9550778B2 </span> <span> . 2017-01-24</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：取代6-芳基-咪唑并吡啶和6-芳基-三唑并吡啶甲酰胺类似物作为mGluR5的负变构调节剂 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130412594595.html">SUBSTITUTED 6-ARYL-IMIDAZOPYRIDINE AND 6-ARYL-TRIAZOLOPYRIDINE CARBOXAMIDE ANALOGS AS NEGATIVE ALLOSTERIC MODULATORS OF MGLUR5</a> <b>[P]</b> . <span> 外国专利：  US2016096833A1 </span> <span> . 2016-04-07</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：取代的6-芳基-咪唑基吡啶和6-芳基-三唑基吡啶酰胺模拟物作为MGLUR5的负变位调节剂 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130473820550.html">Condensation products of a-aminoisopropyl phenyl ketone, via the C=O carbonyl bond, with substituted amines, functionally substituted hydrazines or derivatives of natural amino acids, having an anticancer activity</a> <b>[P]</b> . <span> 外国专利：  FR2540868A1 </span> <span> . 1984-08-17</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：α-氨基异丙基苯基酮通过C = O羰基键与具有抗癌活性的取代胺，官能取代的肼或天然氨基酸衍生物的缩合产物 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704025793750','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> <h2>期刊订阅</h2> <img src="https://cdn.zhangqiaokeyan.com/img/loginclose.png" alt="" onclick="$('.journalsub-pop-up').hide()"> <p class="pardon">抱歉，该期刊暂不可订阅，敬请期待！</p> <p class="current">目前支持订阅全部北京大学中文核心（2020）期刊目录。</p> <div style="display: flex;margin-top: 69px;justify-content: space-between;"> <div class="no-sub" onclick="$('.journalsub-pop-up').hide()">暂不订阅</div> <div class="other-sub" onclick="continueSub('from=pc-detail')">继续订阅其他期刊</div> </div> </div> </div> <div class="right_btn"> <ul> <li class="gouwuche">  </li> <li class="yijian"> <a href="javascript:void(0);" onclick="link_analysis('/mycenter/auth/complaint.html',this)">意见反馈</a> </li> <li class="top"> <a href="javascript:scrollTo(0,0);">回到顶部</a> </li> <li class="shouye"> <a href="/">回到首页</a> </li> </ul> </div> <div class="xllindexfooter"> <div class="xllindexfootercenter"> <div class="xllindexfooterleft left" > <div class="xllindexfooterleftli"> <ul> <li><a href="/about.html">关于掌桥</a></li> <li><a href="/help/helpmap.html">资源导航</a></li> <li><a href="/help/helpguide.html">新手指南</a></li> <li><a href="/help/helpcenter.html">常见问题</a></li> <li><a href="/sitemap.html">网站地图</a></li> <li><a href="/help/helpcenter.html?type=9">版权声明</a></li> </ul> </div> <div class="xllindexfooterleft"> <p class="xllindexfooterlefteamil">客服邮箱：kefu@zhangqiaokeyan.com</p> <div class="xllindexfooterlefttcp"> <div class="xllindexfooterpoliceiimg"></div> <div class="xllindexfooterpoliceispan"> <span>京公网安备：11010802029741号 </span> <span>ICP备案号：<a href="https://beian.miit.gov.cn" rel="nofollow" target="_blank">京ICP备15016152号-6</a></span> <span>六维联合信息科技 (北京) 有限公司©版权所有</span> </div> </div> </div> </div> <div class="xllindexfooterright left"> <ul> <li> <p style="font-weight: bold;">客服微信</p> <div></div> </li> <li> <p style="font-weight: bold;">服务号</p> <div></div> </li> </ul> </div> </div> </div> <span id="0704025793750down" data-source="7," data-out-id="tqLL277Ab3t3ROv3Tlkiyh2HzLoBhtDglp7OJTb/iGpAIcxNcI8o5MlOVW1zthBm," data-f-source-id="7" data-title="A natural bond orbital analysis of aryl‐substituted polyfluorinated carbanions: negative hyperconjugation" data-price="20" data-site-name="" data-transnum="24" style="display:none;"></span> <input type="hidden" value="4" id="sourcetype"> <input type="hidden" value="35546" id="journalid"> <input type="hidden" value="https://cdn.zhangqiaokeyan.com" id="imgcdn"> <input type="hidden" value="1" id="isdeatail"> <input type="hidden" value="" id="syyn_indexed_database"> <input type="hidden" value="" id="servicetype"> <input type="hidden" id="pagename" value="A natural bond orbital analysis of aryl‐substituted polyfluorinated carbanions: negative hyperconjugation"/> <input type="hidden" value="thesis_get_original" id="pageIdentification"> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery-1.12.4.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/lwlh_ajax.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zq.js?v=5.7.6"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/common.js?v=5.7.6"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery.cookie.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/top.js?v=5.7.6"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/tip.js?v=5.7.6"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/login.js?v=5.7.6"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/down.js?v=5.7.6"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/search.js?v=5.7.6"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/searchtype.js?v=5.7.6"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/user/regist.js?v=5.7.6"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zxs_solor/detail.js?v=5.7.6"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/statistics/static/pagecollection.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/tj.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/pushbaidu.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/history.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/util/cookie.js?v=5.7.6"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/weipu/weipu.js?v=5.7.6"></script> </body> <script> $(function(){ var weiPuStatus = getCookie('WeiPuStatus'); if(weiPuStatus){ tipWeiPuStatus(weiPuStatus); delCookie('WeiPuStatus'); } getFacetKeywordVoInId(); var sourcetype = $("#sourcetype").val(); if(sourcetype ==1||sourcetype==4){ getJournal(); } }) </script> </html>