Fracto-mechanoluminescent light emission of EuD(4)TEA-PDMS composites subjected to high strain-rate compressive loading

摘要

The objective of this study is to understand light emission characteristics of fracto-mechanoluminescent (FML) europium tetrakis(dibenzoylmethide)-triethylammonium (EuD(4)TEA) crystals under high strain-rate compressive loading. As a sensing material that can play a pivotal role for the self-powered impact sensor technology, it is important to understand transformative light emission characteristics of the FML EuD(4)TEA crystals under high strain-rate compressive loading. First, EuD(4)TEA crystals were synthesized and embedded into polydimethylsiloxane (PDMS) elastomer to fabricate EuD(4)TEA-PDMS composite test specimens. Second, the prepared EuD(4)TEA-PDMS composites were tested using the modified Kolsky bar setup equipped with a high-speed camera. Third, FML light emission was captured to yield 12 bit grayscale video footage, which was processed to quantify the FML light emission. Finally, quantitative parameters were generated by taking into account pixel values and population of pixels of the 12 bit grayscale images to represent FML light intensity. The FML light intensity was correlated with high strain-rate compressive strain and strain rate to understand the FML light emission characteristics under high strain-rate compressive loading that can result from impact occurrences.