A new route to (N)_n-donor functionalised phosphines; novel homo- and hetero-nuclear complexes of a phosphino-substituted triazacyclononane ligand

Scott E. Watkins; Xinhao Yang; Donald C. Craig; Stephen B. Colbran

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A new route to (N)_n-donor functionalised phosphines; novel homo- and hetero-nuclear complexes of a phosphino-substituted triazacyclononane ligand

机译：（N）_n-供体功能化膦的新途径;膦基取代的三氮杂环壬烷配体的新型同核和杂核配合物

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A phosphino-substituted triazacyclononane ligand, oPtacn, has been prepared by a new, potentially versatile route, the complexes [Cu~I(oPtacn)][PF_6], [Pt~(II)Cl_2{H(oPtacn)}_2][PF_6]_2 and [Pt~(II)Cl_2{(oPtacn)[Cu_(II)(OAc)]}_2][PF_6]_2 made, and the crystal structure of [Cu~I(oPtacn)][PF_6] determined.

机译：膦取代的三氮杂环壬烷配体oPtacn，是通过一种新的，可能具有通用性的途径制备的，其络合物为[Cu〜I（oPtacn）] [PF_6]，[Pt〜（II）Cl_2 {H（oPtacn）} _ 2] [制备了PF_6] _2和[Pt〜（II）Cl_2 {（邻苯二甲酸）[Cu_（II）（OAc）]} _ 2] [PF_6] _2，并确定了[Cu〜I（oPtacn）] [PF_6]的晶体结构。

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《Journal of the Chemical Society, Dalton Transactions. Inorganic Chemistry》 |1999年第10期|共2页
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Scott E. Watkins; Xinhao Yang; Donald C. Craig; Stephen B. Colbran;
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1. A new route to (N)_n-donor functionalised phosphines; novel homo- and hetero-nuclear complexes of a phosphino-substituted triazacyclononane ligand [J] . Scott E. Watkins, Xinhao Yang, Donald C. Craig, Journal of the Chemical Society, Dalton Transactions. Inorganic Chemistry . 1999,第10期

机译：（N）_n-供体功能化膦的新途径;膦基取代的三氮杂环壬烷配体的新型同核和杂核配合物
2. A new routo to (N)_n-donor functionalised phosphines:novel homo-and hetero-nuclear complexes of a phosphino-substituted triazacyclononane ligand [J] . Watkins Scott E., Yang Xinhao Journal of the Chemical Society. Dalton Transactions . 1999,第10期

机译：（N）_n-供体官能化的膦的新路线：膦基取代的三氮杂环壬烷配体的新的同核和异核配合物
3. A new routo to (N)_n-donor functionalised phosphines:novel homo-and hetero-nuclear complexes of a phosphino-substituted triazacyclononane ligand [J] . Watkins Scott E., Yang Xinhao Journal of the Chemical Society. Dalton Transactions . 1999,第10期

机译：（N）_n-供体官能化的膦的新路线：膦基取代的三氮杂环壬烷配体的新的同核和异核配合物
4. Synthesis of a tetranuclear vanadium cubane-type cluster protected by Co(III) complexes with 1,4,7-triazacyclononane ligands [C] . Keisuke Kawamoto, Sugiarto, Yoshihito Hayashi 日本化学会春季年会講演予稿集 . 2018

机译：由CO（III）配合物保护的四核钒嵌合型簇与1,4,7-三氮杂环烷配体保护
5. Synthesis, structrual characterization and reactivity of late transition metal complexes containing P,N-donor phosphine ligands. [D] . Song, Haibin. 2002

机译：含P，N-供体膦配体的后期过渡金属配合物的合成，结构表征和反应活性。
6. CO and O2 Binding to Pseudo-Tetradentate Ligand-Copper(I)-Complexes with a Variable N-Donor Moiety: Kinetic/Thermodynamic Investigation Reveals Ligand Induced Changes in Reaction Mechanism [O] . Heather R. Lucas, Gerald J. Meyer, Kenneth D. Karlin -1

机译：CO和O 2绑定到伪四齿配体 - 铜（I）-Complexes具有可变的N-供体部分：动力学/热力学研究揭示了反应机理配体诱导的变化
7. Oxidation of Sulfide, Phosphine, and Benzyl Substrates Tethered to N-Donor Ligands in Carboxylate-Bridged Diiron(II) Complexes [O] . -1

机译：硫化物，膦和苄基底物的氧化在羧酸桥（II）复合物中纳入N-供体配体

A new route to (N)_n-donor functionalised phosphines; novel homo- and hetero-nuclear complexes of a phosphino-substituted triazacyclononane ligand

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