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Synthesis of a tetranuclear vanadium cubane-type cluster protected by Co(III) complexes with 1,4,7-triazacyclononane ligands

机译：由CO（III）配合物保护的四核钒嵌合型簇与1,4,7-三氮杂环烷配体保护

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Vanadium(V) oxide, V2O5, as one of the metal oxides plays an important role for an oxidation catalyst of various substances. It has a sheet structure constructed by the combination of V2O2 dimer units. The M2O2 dimer units are a basic framework of almost all cluster structures.

机译：钒（V）氧化物V2O5，作为金属氧化物之一对各种物质的氧化催化剂起着重要作用。它具有由V2O2二聚体单元的组合构成的片状结构。 M2O2二聚体单元是几乎所有簇结构的基本框架。

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来源
《日本化学会春季年会講演予稿集》|2018年|1 CD-ROM|共1页
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Keisuke Kawamoto; Sugiarto; Yoshihito Hayashi;
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中图分类石油化学工业;
关键词
Cubane-type cluster; vanadium; tacn; mixed-valence;

机译：Cubane型集群;钒;TACN;混合价;

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1. Synthesis, characterization, and acidity of ruthenium dihydrogen complexes with 1,4,7-triazacyclononane, 1,4,7-trimethyl-1,4,7-triazacyclononane, and hydrotris(pyrazolyl)borato ligands [J] . Ng SM., Lau CP., Wong WT., Organometallics . 1998,第10期

机译：1,4,7-三氮杂环壬烷，1,4,7-三甲基-1,4,7-三氮杂环壬烷和氢三（吡唑基）硼酸酯配体的钌二氢配合物的合成，表征和酸度
2. Iron(III), nickel(II) and cadmium(II) complexes of triazamacrocyclic ligand with pendant nitrile groups 1,4,7-tris(cyanomethyl)-1,4,7-triazacyclononane: Synthesis, structural characteristics and artificial nuclease activity [J] . Zhang Z, Geng ZR, Kan XW, Inorganica Chimica Acta . 2010,第8期

机译：具有侧基腈基1,4,7-三（氰甲基）-1,4,7-三氮杂环壬烷的三氮杂大环配体的铁（III），镍（II）和镉（II）配合物：合成，结构特征和人工核酸酶活性
3. Synthesis, Structure, and Reactivity of Mixed-Ligand Dinuclear Ruthenium Polyhydrido Complexes Supported by 1,4,7-Trimethyl- 1,4,7-triazacyclononane and Bulky Phosphine Ligands [J] . Kyo Namura, Hiroharu Suzuki Organometallics . 2014,第12期

机译：1,4,7-三甲基-1,4,7-三氮杂环壬烷和大宗膦配体负载的混合配体双核钌多氢配合物的合成，结构和反应性
4. Synthesis of a tetranuclear vanadium cubane-type cluster protected by Co(III) complexes with 1,4,7-triazacyclononane ligands [C] . Keisuke Kawamoto, Sugiarto, Yoshihito Hayashi 日本化学会春季年会講演予稿集 . 2018

机译：由CO（III）配合物保护的四核钒嵌合型簇与1,4,7-三氮杂环烷配体保护
5. PART I; PEPTIDE SYNTHESIS UTILIZING THE INORGANIC PROTECTING GROUP PENTAAMMINECOBALT(III). PART II; A STUDY OF COBALT AND RUTHENIUM COMPLEXES WITH BINUCLEAR CHELATING LIGANDS AS INTERMEDIATES FOR WATER OXIDATION. [D] . LYON, JOHN MICHAEL. 1983

机译：第一部分利用无机保护基五氨合钴（III）合成肽。第二部分含双核螯合物的钴和钌配合物作为水氧化中间体的研究。
6. Strategic Isolation of a Polyoxocation Mimicking Vanadium(V) Oxide Layered-Structure by Stacking of H2V2O84− Anions Bridged by (147-Triazacyclononane)Co(III) Complexes [O] . Sugiarto, Keisuke Kawamoto, Yoshihito Hayashi 2018

机译：通过堆叠由（147-三氮杂环壬烷）Co（III）络合物桥接的H2V2O8 4-阴离子堆叠的模拟氧化钒（V）分层结构的策略分离
7. Synthesis, characterization, and acidity of ruthenium dihydrogen complexes with 1,4,7-triazacyclononane, 1,4,7-trimethyl-1,4,7-triazacyclononane, and hydrotris (pyrazolyl)borato ligands [O] . Ng SM, Fang YQ, Lau CP, 1998

机译：具有1,4,7-三氮杂环壬烷，1,4,7-三甲基-1,4,7-三氮杂环壬烷和氢三（吡唑基）硼酸酯配体的钌二氢配合物的合成，表征和酸度

Synthesis of a tetranuclear vanadium cubane-type cluster protected by Co(III) complexes with 1,4,7-triazacyclononane ligands

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