Electrochemical investigation of copper chemical mechanical planarization in alkaline slurry without an inhibitor

摘要

This work investigates the static corrosion and removal rates of copper as functions of H_2O_2 and FA/OIIconcentration, and uses DC electrochemical measurements such as open circuit potential (OCP), Tafel analysis, as well as cyclic voltammetry (CV) to study H_2O_2 and FA/OIIdependent surface reactions of Cu coupon electrode in alkaline slurry without an inhibitor. An atomic force microscopy (AFM) technique is also used to measure the surface roughness and surface morphology of copper in static corrosion and polishing conditions. It is shown that 0.5 vol.% H_2O_2 should be the primary choice to achieve high material removal rate. The electrochemical results reveal that the addition of FA/O II can dissolve partial oxide film to accelerate the electrochemical anodic reactions and make the oxide layer porous, so that the structurally weak oxide film can be easily removed by mechanical abrasion. The variation of surface roughness and morphology of copper under static conditions is consistent with and provides further support for the reaction mechanisms proposed in the context of DC electrochemical measurements. In addition, in the presence of H_2O_2, 3 vol.% FA/O II may be significantly effective from a surface roughness perspective to obtain a relatively flat copper surface in chemical mechanical planarization (CMP) process.