Equilibrium solubility of carbon dioxide in (2-amino-2-methyl-1-propanol + piperazine + water)

摘要

In this work, a new set of values for the solubility of carbon dioxide in aqueous mixture containing different concentrations of 2-amino-2-methyl-1-propanol (AMP), a sterically-hindered amine, and piperazine (PZ), an activator, are presented. The results were carefully determined using a 1.0 dm~3 stainless steel vapour-recirculation equilibrium cell at T = (313.2, 333.2, and 353.2) K, and pressures up to 152 kPa. The AMP concentrations in the ternary (solvent) mixture were (2 and 3) kmol · m~(-3); those of PZ's were (0.5, 1.0, and 1.5) kmol · m~(-3). The measured equilibrium loading (solubility)/partial pressure pairs at different temperatures and concentration levels were generally consistent with the corresponding values correlated from the Kent-Eisenberg model that has been adapted for the system in the study, where the parameters of the models were determined using the results from this study and relevant data from literature.