Experimental and theoretical investigation of solubility of carbon dioxide in concentrated aqueous solution of 2-amino-2-methyl-1-propanol and piperazine

摘要

In this work, new experimental results for the (vapour + liquid) equilibrium (VLE) of CO _2 in piperazine (PZ)-activated concentrated aqueous 2-amino-2-methyl-1-propanol (AMP) are presented for the temperature range of (303 to 328) K and PZ concentration range of (2 to 8) wt.%, keeping the total amine concentration in the solution at 40% and 50 wt.%. The partial pressures of CO _2 are in the range of (0.2 to 1500) kPa. The electrolyte non-random two-liquid (ENRTL) theory has been used to develop the VLE model for the quaternary system (CO _2 + AMP + PZ + H _2O) to describe the equilibrium behaviour of the solution. The CO _2 cyclic capacity of these solvents is determined between the rich and lean CO _2 loadings. It is found that the CO _2 cyclic capacity increases with the addition of PZ in aqueous AMP and also with the increase in AMP concentration in the aqueous solution. However, solid precipitation has been observed for 50 wt.% total amine concentration below T = 318 K for all relative compositions of AMP and PZ in the solvent at higher CO _2 loading. The model results of equilibrium composition, pH of the loaded solution and amine volatility of the mixed solvent system, are also presented.