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(7,8-Dimethyl-2-oxo-2H-chromen-4-yl)methyl piperidine-1-carbodi-thio-ate

机译:(7,8-二甲基-2-氧代-2H-铬-4-基)甲基哌啶-1-Carbodi-Thio-ate

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摘要

In the title compound, C 18 H 21 NO 2 S 2 , the 2 H -chromene ring systems is nearly planar, with a maximum deviation of 0.023?(2)??. The coumarin unit makes a dihedral angle of 60.54?(8)° with the piperidine ring, which adopts a chair conformation. The carbodi-thio-ate group is present in a synperiplanar conformation with respect to the piperidine ring, as indicated by the torsion angle of ?4.7?(2)°. A short intra-molecular C—H?S conatct generates an S (5) ring. No directional inter-actions beyond van der Waals contacts could be identified in the crystal.
机译:在标题化合物中,C 18 H 21 No 2 S 2,2 H-氯丙烯环系统几乎是平面的,最大偏差为0.023?(2)。香豆素单位具有60.54的二偏角角度(8)°,用哌啶环,采用椅子构象。碳二硫代氨基酮基团在同哌啶环中存在于哌啶环中,如π.7?(2)°的扭转角度所示。短暂的分子内C-H·S圆锥图案产生S(5)环。可以在晶体中识别超越范德瓦尔斯联系人的方向性互动。

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