Electrochemical behavior and electrodeposition of Ni-Co alloy from choline chloride-ethylene glycol deep eutectic solvent

摘要

In this work, nickel-cobalt (Ni-Co) alloy was prepared in choline chloride-ethylene glycol deep eutectic solvent by deposition. Metal ion complex structure and stability were studied using UV-Vis. The electrochemical behavior in different metal salts was studied by voltammetry (CV) and chronoamperometry (CA). The corrosion resistance was studied using potentiodynamic polarisation and electrochemical impedance (EIS). Surface and phase composition of Ni-Co alloy coatings were characterized by scanning electron microscopy (SEM/EDS) and X-ray diffraction (XRD). The results from the voltammetry showed that the reduction peak appear among -0.6 V similar to-1.13 V, which belonged to Ni-Co codeposition. The reduction of Ni-Co alloy in the CE was an irreversible process under diffusion control. Chronoamperometric results indicated that the electrodeposition of Ni-Co on a glassy carbon electrode followed the mechanism of instantaneous nucleation and three-dimensional growth. The results of microstructure and phase composition showed that the control of deposition potential could effectively control the microstructure and Co content of Ni-Co alloy. Nano crystal structure could be obtained with a grain size in the range of 3.1-4.0 nm. Comparison in the corrosion behaviour of the coatings showed that the change of Co content had an effect on the corrosion resistance of Ni-Co alloy.