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Viscoelastic Properties of Rubber Composites Reinforced by Wheat Gluten and Wheat Starch Co-filler

机译:小麦麸质和小麦淀粉共填充物加固橡胶复合材料的粘弹性

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摘要

For practical applications (tires,seals,dampers,etc),carbon black (CB) derived from petroleum or natural gas is the dominating filler used to reinforce crosslinked rubber materials. Renewable agricultural materials are alternative sources for a sustainable economy. In this study,agricultural materials are investigated as reinforcement fillers in rubber composites. Some renewable materials such as soy protein isolate [1],defatted soy flour [2],soy protein concentrate [3],and soy spent flakes [4] were shown to be effective in increasing rubber modulus. It was also observed that different reinforcement effects were obtained from these soy products that had different protein/carbohydrate ratios [2,3]. In this study,wheat gluten and wheat starch were mixed in different ratios as a co-filler and their effects on the viscoelastic properties of rubber composites were investigated. To simplify the studies,the polymer matrix used in this study was styrene-butadiene (SB) latex with a small amount of carboxylic acid containing monomer units. The carboxylated SB forms a crosslinked polymer matrix by the aggregation of ionic functional groups without the complication of covalent reactions. In practical applications,conventional rubber formulations including different types of rubber latices,crosslinking agents,coupling agents,plasticizers,etc. may also be used.
机译:对于实际应用(轮胎,密封件,阻尼器等),来自石油或天然气的炭黑(CB)是用于加强交联橡胶材料的主导填料。可再生农产品是可持续经济的替代来源。在这项研究中,将农业材料作为橡胶复合材料中的增强填料进行研究。一些可再生材料如大豆蛋白分离物[1],脱脂大豆粉[2],大豆蛋白浓缩物[3],以及大豆花液[4]在增加橡胶模量方面有效。还观察到,从具有不同蛋白质/碳水化合物比率的这些大豆产品获得不同的增强效果[2,3]。在本研究中,小麦麸质和小麦淀粉以不同的比例混合,作为共填充物,研究了对橡胶复合材料的粘弹性性能的影响。为了简化研究,本研究中使用的聚合物基质是苯乙烯 - 丁二烯(Sb)胶乳,含有少量含有单体单元的羧酸。羧化的Sb通过离子官能团的聚集而形成交联聚合物基质,而无需共价反应并发症。在实际应用中,传统的橡胶配方包括不同类型的橡胶胶乳,交联剂,偶联剂,增塑剂等。也可以使用。

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