Raman Spectroscopic Investigations of Noncovalent Interactions between Pyrimidine and Hydrogen Bonded Networks

摘要

Noncovalent interactions are prevalent in nature and dictate the physical properties of many important molecular systems. Hydrogen bonding represents the most extensively investigated class of noncovalent interactions because of its importance in the chemical and physical properties of water as well as its impact on the structure and function of biomolecules including amino acids, nucleotides, monosaccharides, and polymers formed from these molecules.1 Hydrogen bonding also plays a dominant role in determining crystal structure, salvation phenomena, reaction dynamics in liquids, nonlinear optical responses in solid state materials, surface and electrode chemistry, and the macroscopic properties of gases and condensed phase materials.