首页> 外文会议>Clearwater clean coal conference;International technical conference on clean coal fuel systems >OXYCOAL-AC: Towards the Realisation of a Coal-Fired Power Plant Process with Membrane-based Oxygen Supply - a Survey of Accumulated Experience
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OXYCOAL-AC: Towards the Realisation of a Coal-Fired Power Plant Process with Membrane-based Oxygen Supply - a Survey of Accumulated Experience

机译:OXYCOAL-AC:通过膜式氧气供应实现燃煤电厂过程-积累的经验调查

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The OXYCOAL-AC research project aims at the development of the main components for an integratedpower plant process based on burning pulverized fuel in a mixture of recirculated flue gas (RFG) andoxygen. The oxygen is produced by a ceramic membrane-based air separation. The paper presents thecurrent status of the project, focusing on the main subprojects namely stability of oxy-flames, design ofoxycoal swirl burners, cleaning of the recycled hot flue gas and heat transfer in a utility scale oxy-firedfurnace.The development, experimental tests and scale up of a pilot scale oxy-fired swirl burner, able to operate inoxy-firing as well as in air firing atmospheres are shown. Measures for oxy-flame stabilization as a functionof flue gas recycling ratio (O_2 content) are derived and the design of a swirl burner able to stable operationin both air and oxy-firing has been developed. With this status reached, OXYCOAL-AC is the first pilottest-plant where coal can be burnt in a stable flame in a CO_2 atmosphere with an oxygen content betweenas low as 18 % up to above 30 % for both dry and wet recycle.The hot flue gas leaving the boiler in the OXYCOAL-AC process (containing fly ash, sulphur dioxide andalkali metal compounds) must be cleaned before reaching the membrane module. In order to reduce theefficiency losses, the RFG is cleaned at temperature levels defined by the membrane operation. For thispurpose, a hot gas cleaning vessel is connected through insulated hot gas piping with the furnaceexhaust. Pilot tests were conducted using different filter candles. First experiments have shown that attemperatures above approximately 500°C, the softening of the fly ash impedes back pulse filter cleaningthus causing major problems. As the ash’s alkali content has a high impact on the softening temperatureof the ash, an addition of alkali getter materials (alumina-silicate) to the coal led to a reduction ofmeasured Na~+ and K~+ concentrations in the gas phase. Thus the adhesiveness and the stickiness of thefly ash at high temperatures (around 800°C) can be reduced. Based on this it is expected that animprovement in the hot gas de-dusting process can be achieved, however, further experiments provingthis are needed.Further, numerical simulations of utility scale (1200 MW_(th)) boiler oxy-firing bituminous coal, based on nongreyimplementation of Exponential Wide Band Model, were performed with respect to retrofit.Comparisons are made between air firing and oxy- firing under boundary conditions varying with respectto oxygen and water content of the oxidizer. Predictions have shown that a significant increase of theoxygen concentration in the O_2/RFG mixture (approx. 27% for wet recycle and 30% for dry recycle) isnecessary for compensation of the higher molar heat capacity of CO_2 and thus for obtaining the similarflame temperatures as those in air-firing. However, due to the changed optical density of the flue gas, thiswill lead to 16 % increase of the incident radiation to the furnace walls in case of wet recycle and 5% fordry recycle. The results have shown that similar heat transfer in the combustion chamber to those in airfiringcan be achieved with an oxygen enrichment of recycled flue gas to around 24 vol.-% for wet and toaround 29 vol.-% for dry recycle respectively.
机译:墨粉 - 交流研究项目旨在开发集成的主要组件 基于燃烧的粉碎燃料在再循环烟气(RFG)的混合物中的电厂工艺 氧。氧通过陶瓷膜的空分离产生。本文呈现 项目的当前状态,专注于主要子项目即氧气稳定性,设计 氧气旋流燃烧器,清洁再生热烟道气和氧化实用规模的热传递氧气 炉。 开发,试验试验和扩展飞行型氧气闪燃旋流燃烧器,能够运行 显示氧气以及空气烧制气氛。作为函数的氧气稳定措施 烟道气回收率(O_2含量)是推导的,并且能够稳定运行的旋流燃烧器的设计 在空气和吹气中开发出来。通过这种状态达到,oxocoal-ac是第一个飞行员 试验厂,其中煤可以在稳定的火焰中燃烧在CO_2大气中,含氧含量 干燥和湿润再循环低至高达18%高达30%。 热烟气在含氧燃料 - 交流方法中留下锅炉(含粉煤灰,二氧化硫和 在到达膜组件之前,必须清洁碱金属化合物。为了减少 效率损失,RFG在由膜操作定义的温度水平下清洁。为了这 目的,通过带炉子的绝缘热气体管道连接热气体清洁容器 排气。使用不同的过滤蜡烛进行试验试验。第一个实验表明在 温度高于约500°C,粉煤灰的软化阻碍了脉冲滤波清洁 从而造成重大问题。随着灰碱含量对软化温度的影响很高 灰烬,将碱(氧化铝硅酸盐)添加到煤中导致减少 测量气相中的Na〜+和K〜+浓度。因此,粘合性和粘性 高温(约800°C)的粉煤灰可以减少。基于此,预计这是一个 然而,可以实现热气体去除尘过程的改进,但是进一步的实验证明 这是需要的。 此外,基于非GREY的公用事业量表(1200 mW_(TH))锅炉吹烟煤的数值模拟 关于改造的实施指数宽带模型的实现。 在尊重的边界条件下,在空气烧制和吹入之间进行比较 氧化剂的氧气和含水量。预测表明,显着增加了 O_2 / RFG混合物中的氧气浓度(约27%湿回收,干再循环30%)是 补偿CO_2更高摩尔热容量所必需的,从而获得类似的 火焰温度作为燃气中的气温。但是,由于烟道气的改变的光密度,这 在湿回收的情况下,将导致入射辐射的16%增加到炉壁,5% 干回收。结果表明,燃烧室中的类似传热与空气中的相似 可以通过氧气富含回收的烟气来实现,以至于24体积约24体积%.-%潮湿和 大约29体积%.-%的干回收。

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