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Effect of maltodextrins on water adsorption and glass transition of spray dried soy sauce powders

机译:麦芽糊精对喷雾干燥酱油粉的吸水率和玻璃化转变的影响

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Soy sauce powders were made by spray drying liquid soy sauce using maltodextrin as the drying aid.Maltodextrins of DE 5, DE 10 and DE 15 with concentrations of 20% and 40% (w/v) were incorporated intothe soy sauce, respectively, as a carrier. The moisture adsorption isotherms of the powders with and withoutmaltodextrins were studied. T_g of the powders were determined using a differential scanning calorimeter(DSC) after being equilibrated under various water activities. Brunauer-Emmett-Teller (BET) equation andGordon-Taylor equation were used to model the experimental data of moisture adsorption and T_g,respectively. It was found that the spray dried soy sauce powder was very hygroscopic in nature.Incorporating maltodextrins could significantly reduce the hygroscopicity of the soy sauce powders, withhigher maltodextrin concentration resulting in lower equilibrium moisture content. The BET equation wasfound to be able to model the moisture adsorption results of all soy sauce powders up to a_w of 0.84. Theplasticizing effect of water on the glass transition temperature of soy sauce powders was observed. Increasingequilibrium moisture content could significantly reduce the value of T_g. The experimental data of T_g fitted theGordon-Taylor model well. The predicted T_g value of soy sauce dry matter was at 45.4°C which was muchlower than that of the soy sauce powders added with 40% maltodextrins.
机译:使用麦芽糊精作为干燥助剂,通过喷雾干燥液体酱油制得酱油粉。 将浓度为20%和40%(w / v)的DE 5,DE 10和DE 15的麦芽糊精掺入 酱油分别作为载体。有和没有粉末的吸湿等温线 研究了麦芽糊精。使用差示扫描量热仪测定粉末的T_g (DSC)在各种水活动下达到平衡后。 Brunauer-Emmett-Teller(BET)方程和 使用Gordon-Taylor方程对水分吸附和T_g的实验数据进行建模, 分别。发现喷雾干燥的酱油粉末在本质上非常吸湿。 掺入麦芽糖糊精可显着降低酱油粉的吸湿性, 麦芽糊精浓度较高,导致平衡水分含量较低。 BET方程为 被发现能够模拟所有酱油粉末的水分吸附结果,直到a_w达到0.84。这 观察到水对酱油粉的玻璃化转变温度的增塑作用。越来越多 平衡水分含量可以显着降低T_g的值。 T_g的实验数据符合 Gordon-Taylor模型很好。酱油干物质的预测T_g值为45.4°C 低于添加了40%麦芽糖糊精的酱油粉。

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