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Synthetic saponite-derivatives, a method for preparing such saponites and their use in catalytic (hydro) conversions

机译:合成皂苷衍生物,其制备方法及其在催化(水)转化中的用途

摘要

The invention relates to saponite derivatives according to the general formulaA <mrow><mfrac linethickness="0"><mrow><mtext>n+</mtext></mrow><mrow><mtext>x/</mtext></mrow></mfrac></mrow> n[(Mg3-yMy)(Si4-xAlx)O₁₀(OH2-z)Fz]wherein A represents an (alkyl-substituted) ammonium ion and/or any metal having basic or amphoteric properties, M represents a bivalent metal ion having an ionic radius between 0.050 and 0.085 nm, n represents the valence of A, x represents a number between 0.05 and 1.5, y represents a number between 0.05 and 2.95 and z represents a number from 0 to 1.8. The invention also relates to methods for preparing such saponite-­derivatives, catalytically active systems based on such saponite-derivatives and their use in various hydro­carbon conversion processes.
机译:本发明涉及一种通式的皂苷衍生物A <数学id =“ matha01”> <数学文本> <![CDATA [ n + x / ]]> <图像文件=“ IMGA0001.GIF” he =“ 5” id =“ ia01” imgContent =“ math” imgFormat = “ GIF” inline =“ yes” wi =“ 3” /> n [(Mg 3-y M y ) (Si 4-x Al x )O₁₀(OH 2-z )F z ]其中A表示(烷基取代的)铵离子和/或任何具有碱性或两性性质的金属,M表示离子半径在0.050至0.085 nm之间的二价金属离子,n表示A的化合价,x表示0.05和1.5,y代表0.05到2.95之间的数字,z代表0到1.8之间的数字。本发明还涉及制备此类皂石衍生物的方法,基于此类皂石衍生物的催化活性体系及其在各种烃转化方法中的用途。

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