首页> 外国专利> SOLUTION CONTAINING A NITROXIDE RADICAL FOR NUCLEAR MAGNETIC RESONANCE MAGNETOMETRY

SOLUTION CONTAINING A NITROXIDE RADICAL FOR NUCLEAR MAGNETIC RESONANCE MAGNETOMETRY

机译:含核磁共振核磁共振法的氮氧化物自由基的溶液

摘要

The invention relates to a solution containing a nitroxide radical for nuclear magnetic resonance magnetometry. This solution consists of a nitroxide radical of formula: ## STR3 ## in which R ** 1, R ** 2, R ** 3 and R ** 4 which may be identical or different, represent an alkyl group or an optionally deuterated alkoxy group, or in which the pairs R ** 1-R ** 2 and / or R ** 3-R ** 4 together form an optionally deuterated cycloalkyl or polycycloalkyl group, and N represents ** 14N or ** 15N, dissolved in a solvent having an oxidizing power and a suitable viscosity. BR/ The solvent may consist of a mixture of water and two compounds acting respectively as agent oxidizer and viscosity modifier, for example, water, ethylene glycol and NalO4, or be constituted solely by a mixture of water and an oxidizing agent capable of modifying the viscosity such as the acid acetic acid. / P
机译:本发明涉及一种用于核磁共振磁力测定法的含氮氧化物自由基的溶液。该溶液由下式的氮氧化物基团组成:其中R ** 1,R ** 2,R ** 3和R ** 4可以相同或不同,表示烷基或任选地氘代烷氧基,或其中对R ** 1-R ** 2和/或R ** 3-R ** 4一起形成可选的氘代环烷基或多环烷基,并且N代表** 14N或** 15N溶于具有氧化能力和合适粘度的溶剂中。
溶剂可以由水和分别充当试剂氧化剂和粘度调节剂的两种化合物的混合物组成,例如水,乙二醇和NalO4,或仅由水和能够改变粘度,例如酸性乙酸。

著录项

  • 公开/公告号FR2727963A1

    专利类型

  • 公开/公告日1996-06-14

    原文格式PDF

  • 申请/专利权人 COMMISSARIAT A LENERGIE ATOMIQUE;

    申请/专利号FR19940014705

  • 发明设计人 CAROLE BOURBON;MEDHI MOUSSAVI;

    申请日1994-12-07

  • 分类号C07B61/02;G01N24/08;G01N24/10;G01R33/24;

  • 国家 FR

  • 入库时间 2022-08-22 03:40:25

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