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A solution containing a nitroxide radical for magnetometry by resonance magnetic resonance

机译:用于通过共振磁共振进行磁力测定的含氮氧化物自由基的溶液

摘要

The invention relates to a solution containing a nitroxide radical for magnetometry by nuclear magnetic resonance. This solution is constituted by a nitroxide radical of formula: & br / (see appended drawing in bopi) & br / in which r * * 1, r * * 2, r and r * * * 3 * 4, which may be identical or different, represent an alkyl group or an alkoxy group optionally deuterated, or in which the r * * * * r 1 - 2 and / or r * * * * r 3 - 4 together form a polycycloalkyl or cycloalkyl group optionally deuterated, and n * * * * 14n or 15n dissolved in a solvent having an oxidizing agent and an appropriate viscosity. & br / the solvent may be constituted by a mixture of water and of two compounds acting respectively as the oxidizing agent and of the viscosity modifier, for example, of water, ethylene - glycol and nalo4, or be constituted solely by a mixture of water and of an oxidizing agent capable of modifying the viscosity, such as acetic acid.
机译:用于核磁共振的磁力测定法的含氮氧化物的溶液本发明涉及一种用于核磁共振法的磁力测定法的含氮氧自由基的溶液。该溶液由下式的氮氧自由基构成: br />(请参阅bopi中的附图)& br />其中r * * 1,r * * 2,r和r * * * 3 * 4(可以相同或不同)表示烷基或烷氧基,可任选地氘代,或其中r * * * * r 1 -2和/或r * * * * r 3-4一起形成任选地氘代的多环烷基或环烷基,并且n * * * * 14n或15n溶解在具有氧化剂和适当粘度的溶剂中。 &溶剂可以由水和分别起氧化剂作用的两种化合物和粘度调节剂的混合物构成,例如水,乙二醇和纳洛4,或仅由水的混合物构成以及能够改变粘度的氧化剂,例如乙酸。

著录项

  • 公开/公告号FR2727963B1

    专利类型

  • 公开/公告日1997-01-10

    原文格式PDF

  • 申请/专利权人 COMMISSARIAT A L ENERGIE ATOMIQUE;

    申请/专利号FR19940014705

  • 发明设计人 BOURBON CAROLE;MOUSSAVI MEDHI;

    申请日1994-12-07

  • 分类号C07B61/02;G01N24/08;G01N24/10;G01R33/24;

  • 国家 FR

  • 入库时间 2022-08-22 03:12:23

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