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Method for producing layered rock-salt type lithium ferrite by solvothermal ion exchange method

机译:溶剂热离子交换法生产层状岩盐型锂铁氧体的方法

摘要

PROBLEM TO BE SOLVED: To provide a new method capable of mass producing a laminar rock salt type LiFeO2 as a low-cost anode material for a lithium secondary battery. SOLUTION: This method for producing a laminar rock salt type LiFeO2 comprises (1) subjecting -FeOOH to hydrothermal treatment in an aqueous solution of sodium hydroxide at 130-300 deg.C to give a-NaFeO2 and subjecting the compound to solvothermal treatment with an inorganic lithium salt in a nonaqueous solvent at 130-300 deg.C or (2) directly reacting a sodium compound with a ferric compound to give an -NaFeO2 and subjecting the compound to solvothermal treatment with an inorganic lithium salt dispersed into a nonaqueous solvent at 130-300 deg.C.
机译:要解决的问题:提供一种能够大量生产层状岩盐型LiFeO2的新方法,作为锂二次电池的低成本阳极材料。解决方案:这种生产层状岩盐型LiFeO2的方法包括(1)在130-300℃的氢氧化钠水溶液中对-FeOOH进行水热处理,得到α-NaFeO2,然后对该化合物进行溶剂热处理。非水溶剂中的无机锂盐,在130-300℃,或(2)使钠化合物与三价铁化合物直接反应生成-NaFeO2,然后用分散在非水溶剂中的无机锂盐对该化合物进行溶剂热处理。 130-300℃

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