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PROCESS FOR PRODUCING HIGHLY REACTIVE LOW-VISCOSITY MODIFIED PHENOLIC RESINS

机译:制备高反应性低粘度改性酚醛树脂的方法

摘要

Processes for producing highly reactive low viscosity modified phenolic resins include polycondensation of soybean heavy oil or pitch, formaldehyde polymers and phenols in the presence of an acid catalyst to produce modified phenolic resins; Reacting the resulting modified phenolic resin with phenol in the presence of an acid catalyst at a temperature higher than 120 ° C. and not higher than 200 ° C. to lower the molecular weight of the modified phenolic resin. The highly reactive low viscosity modified phenolic resin obtained according to this method has high reactivity with epoxy resin and low resin melt viscosity. Resin can also be used to produce molding materials having good moldability and relatively low water absorption when combined with epoxy resins.
机译:制备高反应性低粘度改性酚醛树脂的方法包括大豆重油或沥青,甲醛聚合物和酚在酸催化剂存在下的缩聚反应,以生产改性酚醛树脂;在酸催化剂的存在下,在高于120℃且不高于200℃的温度下,使所得的改性酚醛树脂与苯酚反应,以降低改性酚醛树脂的分子量。根据该方法获得的高反应性低粘度改性酚醛树脂与环氧树脂的反应性高,树脂熔融粘度低。当与环氧树脂结合使用时,树脂也可用于生产具有良好可模塑性和相对低吸水率的模塑材料。

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