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thermal polymerization of dicyclopentadien

机译:二环戊二烯的热聚合

摘要

The specification discloses a method for making DCPD based resins that have relatively narrow molecular weight distributions. The method comprises thermally polymerizing dicyclopentadiene monomer in the presence of one or more strong acids, preferably with an olefinic modifier, to provide a dicyclopentadiene oligomer. Optionally, an organic sulfur species can also be used to further effect molecular weight control. For end-use performance in inks, adhesives, coatings and other related areas, the invention provides dicyclopentadiene oligomer resins having weight average molecular weights less than 1000 and relatively narrow molecular weight distributions, as measured by a polydispersity index, of less than about 2.3. Among the strong acids that are effective for controlling molecular weight, hypophosphorous acid is preferred because it gives light colored resins.
机译:该说明书公开了一种制备具有相对窄的分子量分布的DCPD基树脂的方法。该方法包括在一种或多种强酸的存在下,优选与烯烃改性剂一起热聚合二环戊二烯单体,以提供二环戊二烯低聚物。任选地,有机硫物质也可以用于进一步实现分子量控制。为了在油墨,粘合剂,涂料和其他相关领域中的最终使用性能,本发明提供了重均分子量小于1000且通过多分散指数测量的相对窄的分子量分布小于约2.3的二环戊二烯低聚物树脂。在可有效控制分子量的强酸中,次磷酸是优选的,因为它可产生浅色树脂。

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