首页> 外国专利> CHEMICAL PRODUCTS SUITED FOR USE AS CO-CATALYSTS, METHOD FOR THE PREPARATION THEREOF AND THEIR USE IN CATALYST SYSTEMS FOR PRODUCING POLYOLEFINS

CHEMICAL PRODUCTS SUITED FOR USE AS CO-CATALYSTS, METHOD FOR THE PREPARATION THEREOF AND THEIR USE IN CATALYST SYSTEMS FOR PRODUCING POLYOLEFINS

机译:适合用作助催化剂的化学产品,其制备方法及其在生产聚烯烃的催化剂体系中的用途

摘要

The invention relates to chemical products which are suited for use as co-catalysts and which can be obtained by reacting a compound of formula (I), MSUP1/SUPRSUP1/SUPRSUP2/SUP(RSUP3/SUP)SUBm /SUBwith a compound of formula (II), (RSUP4/SUPX)SUBq/SUB-(G)*(MSUP2/SUPRSUP5/SUPRSUP6/SUP)SUBg/SUB. In formula (I), RSUP1/SUP, RSUP2 /SUPand RSUP3 /SUPare the same or different and represent a hydrogen atom, CSUB1/SUB-CSUB20 /SUBalkyl, CSUB1/SUB-CSUB20 /SUBalkyl halide, CSUB6/SUB-CSUB20 /SUBaryl, CSUB6/SUB-CSUB20 /SUBaryl halide, CSUB7/SUB-CSUB40 /SUBarylalkyl, CSUB7/SUB-CSUB40 /SUBarylalkyl halide, CSUB7/SUB-CSUB40 /SUBalkylaryl or CSUB7/SUB-CSUB40 /SUBalkylaryl halide; MSUP1 /SUPrepresents an element of the second or third main group of the periodic table of elements, and; m equals 0 or 1, whereby m is equal to 1 when MSUP1 /SUPrepresents an element of the third main group, and m is equal to 0 when MSUP1 /SUPrepresents an element of the second main group. In formula (II), substituents RSUP4/SUPX, which contain hetero atoms, is located on a base body G, and: groups RSUP4 /SUPare the same or different and represent hydrogen, CSUB1/SUB-CSUB20 /SUBalkyl, CSUB1/SUB-CSUB20 /SUBalkyl halide, CSUB6/SUB-CSUB20 /SUBaryl, CSUB6/SUB-CSUB20 /SUBaryl halide, CSUB7/SUB-CSUB40 /SUBarylalkyl, CSUB7/SUB-CSUB40 /SUBarylalkyl halide, CSUB7/SUB-CSUB40 /SUBakylaryl or CSUB7/SUB-CSUB40 /SUBalkylaryl halide; X represents an element of the fourth, fifth or sixth main group of the periodic table of elements; G represents at least bivalent CSUB1/SUB-CSUB20 /SUBalkylene, CSUB1/SUB-CSUB20 /SUBalkylene halide, CSUB1/SUB-CSUB10 /SUBalkylenoxy, CSUB6/SUB-CSUB40 /SUBarylene, CSUB6/SUB-CSUB40 /SUBarylene halide, CSUB6/SUB-CSUB40 /SUBarylenoxy, CSUB7/SUB-CSUB40 /SUBarylalkylene, CSUB7/SUB-CSUB40 /SUBarylalkylene halide, CSUB7/SUB-CSUB40 /SUBalkylarylene, CSUB7/SUB-CSUB40 /SUBalkylarylene halide; MSUP2 /SUPrepresents an element of the fourth, fifth or sixth main group of the periodic table of elements; RSUP5 /SUPand RSUP6/SUP, independent of one another, are the same or different and represent a hydrogen atom, CSUB1/SUB-CSUB20 /SUBalkyl, CSUB1/SUB-CSUB10 /SUBalkoxy, CSUB2/SUB-CSUB10 /SUBalkenyl, CSUB7/SUB-CSUB20 /SUBarylalkyl, CSUB7/SUB-CSUB20 /SUBalkylaryl, CSUB6/SUB-CSUB10 /SUBaryloxy, CSUB1/SUB-CSUB10 /SUBalkyl halide; q is a whole number ranging from 2 to 100, and; g is a whole number ranging from 1 to 100. The invention also relates to a method for preparing the inventive chemical products, and to their use in catalyst systems for producing polyolefins.
机译:本发明涉及适合用作助催化剂的化学产物,其可以通过使式(I)的化合物M 1 R 1 R < SUP> 2 (R 3 m 与式(II)的化合物(R 4 X) q -(G)*(M 2 R 5 R 6 g 。式(I)中,R 1 ,R 2 和R 3 相同或不同,表示氢原子C 1 -C 20 -烷基,C 1 -C 20 卤代烷,C 6 -C 20 芳基,C 6 -C 20 芳基卤,C 7 -C 40 芳基烷基,C 7 -C 40 芳基烷基卤,C 7 -C 40 烷基芳基或C 7 -C 40 烷基芳基卤; M 1 表示元素周期表的第二或第三主组的元素,并且; m等于0或1,其中当M 1 表示第三主族的元素时,m等于1,当M 1 表示元素时,m等于0。第二主要群体在式(II)中,含有杂原子的取代基R 4 X位于基体G上,并且:基团R 4 相同或不同并且表示氢,C 1 -C 20 烷基,C 1 -C 20 卤代烷,C 6 -C 20 芳基,C 6 -C 20 芳基卤,C 7 -C < SUB> 40 芳基烷基,C 7 -C 40 芳基烷基卤,C 7 -C 40 烷基芳基或C 7 -C 40 烷基芳基卤; X代表元素周期表的第四,第五或第六主族的元素; G表示至少二价的C 1 -C 20 亚烷基,C 1 -C 20 亚烷基卤,C < SUB> 1 -C 10 亚烷基氧基,C 6 -C 40 亚芳基,C 6 - C 40 亚芳基卤化物,C 6 -C 40 芳烯氧基,C 7 -C 40 芳基亚烷基,C 7 -C 40 芳基亚烷基卤,C 7 -C 40 烷基亚芳基,C 7 -C 40 烷基亚芳基卤化物; M 2 表示元素周期表的第四,第五或第六个主组的元素; R 5 和R 6 彼此独立,相同或不同,表示氢原子C 1 -C 20 烷基,C 1 -C 10 烷氧基,C 2 -C 10 烯基,C 7 -C 20 芳烷基,C 7 -C 20 烷基芳基,C 6 -C 10 芳氧基,C 1 -C 10 烷基卤; q是2到100的整数,并且g为1至100的整数。本发明还涉及制备本发明化学产品的方法,以及它们在用于生产聚烯烃的催化剂体系中的用途。

著录项

  • 公开/公告号EP1290002B1

    专利类型

  • 公开/公告日2004-01-21

    原文格式PDF

  • 申请/专利权人 BASELL POLYOLEFINE GMBH;

    申请/专利号EP20010943413

  • 发明设计人 SCHOTTEK JOERG;

    申请日2001-05-19

  • 分类号C07F5/00;

  • 国家 EP

  • 入库时间 2022-08-21 22:55:00

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