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Non-aqueous electrochemical element electrode binder solution, electrode mixture, electrode and electrochemical element

机译:非水电化学元件电极粘合剂溶液,电极混合物,电极和电化学元件

摘要

PROBLEM TO BE SOLVED: To stabilize performance for less degradation even if a material remains in an electrode, by using an organic solvent as a non-aqueous electrode binder with HOMO level and LUMO level from ab initio method molecular orbit calculation. SOLUTION: Related to an electric double layer capacitor, a separator 3 is sandwiched between two polarized electrodes 1 and 2, which are sealed between a stainless steel cap 4 and a stainless can 6 containing an electrolyte 5 with a packing 7 in between. Related to an organic solvent constituting a non-aqueous electrode binder solution, an HOMO level from ab initio method molecular orbit calculation is -12 eV or below while an LUMO level is +0.4 eV or above. As a solution for electrolyte, propylene carbonate is common while a quaternary phosphonium salt and a quaternary ammonium salt is common as an electrolyte.
机译:解决的问题:通过使用从头算方法分子轨道计算得出的具有HOMO能级和LUMO能级的有机溶剂作为非水电极粘合剂,即使材料残留在电极中也能稳定性能,减少降解。解决方案:与双电层电容器有关,隔膜3夹在两个极化电极1和2之间,两个极化电极1和2密封在不锈钢盖4和装有电解质5的不锈钢罐6之间,并在其间有填料7。关于构成非水电极粘合剂溶液的有机溶剂,从头算方法的分子轨道计算得出的HOMO能级为-12eV以下,而LUMO能级为+ 0.4eV以上。作为电解质溶液,碳酸亚丙酯是常见的,而季phospho盐和季铵盐是常见的电解质。

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