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GAS-PHASE PROCESS FOR PREPARING HETEROPHASIC PROPYLENE COPOLYMERS

机译:制备异规丙烯共聚物的气相法

摘要

A polymerization process for preparing heterophasic propylene copolymers in two or more gas-phase reactors connected in series, in the presence of a polymerization catalyst comprising a catalytic component based on a titanium compound supported on magnesium halide, the process comprising the following steps: - contacting said catalytic component with an organo-Aluminum compound at a temperature from 5°C to 30°C and a weight ratio propylene/(catalytic component) ranging from 0 to 2.0; - prepolymerizing the catalyst from A) with propylene, optionally in the presence of an inert hydrocarbon solvent; - polymerizing propylene, optionally with an another -olefin comonomer in an amount lower than 15% by weight, to prepare a semicrystalline polymer component; - successively copolymerizing two or more alpha-olefin comonomers CSUB2/SUB-CSUB10/SUB to prepare one or more olefin copolymers having a solubility in xylene higher than 15% by weight; the process being characterized in that the bulk density of the semi-crystalline component of step C) is adjusted at a value lower than 0.40 g/cmSUP3/SUP.
机译:一种在两个或多个串联连接的气相反应器中,在包含基于负载在卤化镁上的钛化合物的催化组分的聚合催化剂的存在下,制备多相丙烯共聚物的聚合方法,该方法包括以下步骤:-接触所述催化组分与有机铝化合物在5℃至30℃的温度下,丙烯/(催化组分)的重量比为0至2.0。 -任选地在惰性烃溶剂存在下,将A)的催化剂与丙烯预聚合; -使丙烯任选地与按重量计低于15%的另一种烯烃共聚单体聚合,以制备半结晶聚合物组分; -依次共聚两种或更多种α-烯烃共聚单体C 2 -C 10 ,以制备一种或多种在二甲苯中的溶解度高于15%(重量)的烯烃共聚物;该方法的特征在于,将步骤C)的半结晶成分的堆积密度调整为低于0.40g / cm 3 的值。

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