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METHOD AND USE OF AMINO-FUNCTIONAL RESINS FOR THE DISMUTATION OF HALOGEN SILANES AND FOR REMOVING FOREIGN METALS
METHOD AND USE OF AMINO-FUNCTIONAL RESINS FOR THE DISMUTATION OF HALOGEN SILANES AND FOR REMOVING FOREIGN METALS
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机译:氨基官能团树脂的扩散和去除异金属的方法和用途
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摘要
The invention relates to a process for dismutating at least one halosilane and reducing the content of extraneous metal and/or a compound containing extraneous metal in the at least one halosilane and in the at least one silane obtained, by contacting at least one halosilane of the general formula I, HnSiClm (I), where n and m are integers and n=1, 2 or 3 and m=1, 2 or 3 and n+m=4, with a particulate, organic, amino-functional resin to obtain at least one silane of the general formula II, HaSiClb (II), where a and b are integers and a=0, 2, 3 or 4 and b=0, 1, 2 or 4 where a+b=4, in one step, in which the content of extraneous metal and/or compounds containing extraneous metal has been reduced compared to the halosilane of the formula I. The invention further provides for the use of this resin for dismutating halosilanes and as an absorbent of extraneous metals or compounds containing extraneous metal in a process for preparing monosilane.
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机译:本发明涉及一种通过使至少一种卤代硅烷中的至少一种卤代硅烷接触而使至少一种卤代硅烷歧化并降低至少一种卤代硅烷和所获得的至少一种硅烷中的杂质金属和/或含有杂质金属的化合物的方法。通式I,HnSiRTI(I),其中n和m为整数,n = 1、2或3,m = 1、2或3,n + m = 4,用颗粒状有机氨基官能团树脂制得至少一种通式II的硅烷HaSiClb(II),其中a和b为整数,a = 0、2、3或4,b = 0、1、2或4其中a + b = 4步骤,其中与式I的卤代硅烷相比,减少了外来金属和/或含有外来金属的化合物的含量。本发明进一步提供了该树脂在使卤代硅烷歧化中的用途以及作为外来金属或化合物的吸收剂的用途。在制备甲硅烷的过程中含有外来金属。
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