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Method for surface modification of grapheneoxide using surface initiated polymerization by microwave irradiation

机译:利用微波辐射的表面引发聚合对氧化石墨烯进行表面改性的方法

摘要

PURPOSE: A method for modifying the surface of graphene oxide by using surface-initiated-polymerization based on the irradiation of electromagnetic waves is provided to shorten times required for surface modifying reaction. CONSTITUTION: A method for modifying the surface of graphene oxide includes the following: graphene oxide is introduced into an organic solvent and is dispersed by ultrasonic wave-based decomposition; the dispersed graphene oxide slurry is mixed with monomers and a catalyst; the mixture is introduced into an electromagnetic wave irradiating device; the mixture is irradiated with electromagnetic waves at a temperature between 80 and 120 degrees Celsius for 20 to 50 minutes to obtain graphene oxide-polymer nano-composite. The organic solvent is one selected from a group including toluene, dichloromethane, dimethyl sulfoxide, dimethyl formamide, tetrahydrofurane, acetone, diethyl ether, ethyl acetate, and hexane. The polymer is poly(benzyl vinyl chloride), poly(vinylidene chloride), or poly(vinyl chloride).
机译:目的:提供一种通过使用基于电磁波辐射的表面引发的聚合反应来改性氧化石墨烯表面的方法,以缩短表面改性反应所需的时间。组成:氧化石墨烯表面的改性方法包括:将氧化石墨烯引入有机溶剂中并通过超声波分解分散;将分散的氧化石墨烯浆料与单体和催化剂混合。将混合物引入电磁波辐照装置中。将混合物在80至120摄氏度的温度下用电磁波照射20至50分钟,以获得氧化石墨烯-聚合物纳米复合材料。有机溶剂是选自包括甲苯,二氯甲烷,二甲基亚砜,二甲基甲酰胺,四氢呋喃,丙酮,乙醚,乙酸乙酯和己烷的组中的一种。该聚合物是聚(苄基氯乙烯),聚(偏二氯乙烯)或聚(氯乙烯)。

著录项

  • 公开/公告号KR101186365B1

    专利类型

  • 公开/公告日2012-09-26

    原文格式PDF

  • 申请/专利权人

    申请/专利号KR20120073826

  • 发明设计人 윤국로;박민수;

    申请日2012-07-06

  • 分类号C01B31/02;B01J19/12;B01J19/10;B82B3;

  • 国家 KR

  • 入库时间 2022-08-21 17:07:24

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