首页> 外国专利> LIGHT-EMITTING NANOPARTICLES HAVING IMPROVED LIGHT EMISSION CHARACTERISTICS AND HAVING ZINC-SILVER-INDIUM-SULFIDE COMPOSITION AND METHOD FOR PREPARING SAME USING COMBINATORIAL CHEMISTRY

LIGHT-EMITTING NANOPARTICLES HAVING IMPROVED LIGHT EMISSION CHARACTERISTICS AND HAVING ZINC-SILVER-INDIUM-SULFIDE COMPOSITION AND METHOD FOR PREPARING SAME USING COMBINATORIAL CHEMISTRY

机译:具有改善的发光特性和具有锌-银-铟-硫化物组成的光发射纳米粒子以及使用组合化学制备相同成分的方法

摘要

The present invention relates to light-emitting nanoparticles having improved light emission characteristics and having a zinc-silver-indium-sulfide composition and to a method for preparing same using combinatorial chemistry. To this end, the present invention provides light-emitting nanoparticles having improved light emission characteristics and having a zinc-silver-indium-sulfide ((ZnxAgyInz)S2)(0≤x≤1, 0≤y≤1, 0.1≤z≤1, x+y+z=1) composition. Furthermore, the present invention provides a method for preparing the light-emitting nanoparticles, comprising: a step (step 1) of constructing a library for a zinc-silver-indium composition; a step (step 2) of introducing a zinc precursor, a silver precursor and an indium precursor and a vulcanizing agent based on the library constructed in step 1 to each of different reactors including a solvent to prepare a metal precursor solution; a step (step 3) of irradiating the metal precursor solution with ultrasonic waves in each reactor prepared by step 2; a step (step 4) of adding an alcohol-based solvent, a hydrocarbon-based solvent or a mixture solvent thereof to the metal precursor solution after the ultrasonic wave irradiation of step 3 so as to precipitate zinc-silver-indium-sulfide particles; a step (step 5) of removing supernatant after the precipitation of the particles in step 4; and a step (step 6) of checking the light emission characteristics of the zinc-silver-indium-sulfide nanoparticles from which the supernatant is removed in step 5. According to the present invention, light-emitting nanoparticles having various compositions can be quickly prepared, and light emission characteristics are checked to find light-emitting nanoparticles optimized to a desired composition.
机译:本发明涉及具有改善的发光特性并且具有锌-银-铟-硫化物组合物的发光纳米颗粒及其使用组合化学制备的方法。为此,本发明提供具有改善的发光特性并且具有锌-银-铟-铟-硫化物((ZnxAgyInz)S 2)(0≤x≤1、0≤y≤1、0.1≤z≤的发光纳米粒子。 1,x + y + z = 1)组成。此外,本发明提供了一种制备发光纳米粒子的方法,包括:构建用于锌-银-铟组合物的库的步骤(步骤1);将基于步骤1中构建的库的锌前体,银前体和铟前体以及硫化剂引入到包括溶剂的每个不同的反应器中以制备金属前体溶液的步骤(步骤2);在步骤2制得的各反应器中,用超声波照射金属前体溶液的步骤(步骤3);在步骤3的超声波照射后,将醇系溶剂,烃系溶剂或它们的混合溶剂添加到金属前体溶液中,使锌-银-铟-硫化物粒子析出的工序(步骤4)。在步骤4中使颗粒沉淀后除去上清液的步骤(步骤5);以及检查在步骤5中去除了上清液的锌-银-铟-硫纳米颗粒的发光特性的步骤(步骤6)。根据本发明,可以快速制备具有各种组成的发光纳米颗粒。并检查发光特性以找到最优化为所需组成的发光纳米粒子。

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