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ANION-EXCHANGE MEMBRANE, AND ELECTROCHEMICAL ELEMENT AND ELECTROCHEMICAL DEVICE HAVING SAME
ANION-EXCHANGE MEMBRANE, AND ELECTROCHEMICAL ELEMENT AND ELECTROCHEMICAL DEVICE HAVING SAME
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机译:阴离子交换膜,电化学元件和电化学装置具有相同的功能
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摘要
Provided is an anion-exchange membrane including: a substrate composed of a film of ultrahigh molecular weight polyolefin; and a graft chain having the following structural unit.;L1 to L5 are each independently a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, an alkanol group having 1 to 4 carbon atoms, or a specific functional group including an anion-exchange group, and an example of the functional group is -Z2-M1-Z1(R1)(R2)(R3). R1 to R3 are directly bonded to Z1 and are each independently an alkyl group having 1 to 8 carbon atoms or an alkanol group having 1 to 8 carbon atoms. M1 is a linear hydrocarbon chain having 3 to 8 carbon atoms, Z1 is a nitrogen atom or a phosphorus atom, and Z2 is a nitrogen atom bonded to one hydrogen atom, an oxygen atom, or a sulfur atom. L6 is a hydrogen atom, a methyl group, or an ethyl group.
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机译:本发明提供一种阴离子交换膜,其包括:由超高分子量聚烯烃膜构成的基材;和由所述高分子量聚烯烃膜构成的基材。具有以下结构单元的接枝链。 <图像文件=“ IMGA0001.GIF” he =“ 50” imgContent =“ chem” imgFormat =“ GIF” wi =“ 40” /> Chemistry>; L 1 < / Sub>至L 5 Sub>分别独立地为氢原子,具有1-4个碳原子的烷基,具有1-4个碳原子的链烷醇基或包括阴离子交换的特定官能团。功能组的例子是-Z 2 Sub> -M 1 Sub> -Z 1 Sub>(R 1 Sub> )(R 2 Sub>)(R 3 Sub>)。 R 1 Sub>至R 3 Sub>直接键合至Z 1 Sub>,并且各自独立地为具有1至8个碳原子的烷基或具有1至8个碳原子。 M 1 Sub>是具有3至8个碳原子的直链烃链,Z 1 Sub>是氮原子或磷原子,Z 2 Sub>是与一个氢原子,一个氧原子或一个硫原子键合的氮原子。 L 6 Sub>是氢原子,甲基或乙基。
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