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Process for producing a nitrile using a catalyst containing antimony and iron

机译:使用含锑和铁的催化剂生产腈的方法

摘要

A compound of the formula SbxFe1Oy (I) in which x varies from 0.4 to 1 inclusive and y varies from 1.6 to 4 inclusive, may be used as a catalyst for catalyzing the ammoxidation reaction of an alcohol of following formula (II) CH2═C(R1)—CH2—OH (II) in which R1 represents a hydrogen atom or a methyl radical, to give nitrile of following formula (III) CH2═C(R1)—C≡N (III) in which R1 has the same meaning as in above formula (II), the said reaction being carried out in the gas phase, the said gas phase comprising at least oxygen and ammonia. The present invention also relates to the process for the ammoxidation of an alcohol of formula (II) employing a compound of formula (I) as catalyst.
机译:可以使用其中x变化为0.4至1以下且y变化为1.6至4以下的式SbxFe1Oy(I)的化合物作为催化下式(II)的醇的氨氧化反应的催化剂。 (R1)-CH2-OH(II),其中R1代表氢原子或甲基,得到下式(III)的腈:CH2 = C(R1)-C = N(III),其中R1具有相同的含义如上式(II)所示,所述反应在气相中进行,所述气相至少包含氧和氨。本发明还涉及使用式(I)的化合物作为催化剂的式(II)的醇的氨氧化方法。

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