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CASCADE ADSORPTION MECHANISM FOR OVERCOMING ACTIVATION ENERGY BARRIER IN OXYGEN REDUCTION REACTION

机译:在氧还原反应中克服活化能障碍的级联吸附机理

摘要

Oxygen reduction reaction (ORR) catalyst have particles of a first ORR catalytic material in interspersed contact with particles of a second ORR catalytic material. The first and second ORR catalytic materials have different d band centers so that oxygen can adsorb rapidly at a first binding site, be partly reduced, and then transfer to a second site at which reduction is completed and water desorption is rapid. This allows the catalyst to avoid limitations of slow reactant binding and/or slow product release.
机译:氧还原反应(ORR)催化剂具有与第二ORR催化材料的颗粒散布接触的第一ORR催化材料的颗粒。第一和第二ORR催化材料具有不同的d带中心,使得氧可以在第一结合位点迅速吸附,被部分还原,然后转移到第二位,还原完成并且水迅速解吸。这允许催化剂避免反应物缓慢结合和/或产物释放缓慢的限制。

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