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SUBSTITUTED ε-IRON OXIDE MAGNETIC PARTICLE POWDER, PRODUCTION METHOD FOR SUBSTITUTED ε-IRON OXIDE MAGNETIC PARTICLE POWDER, GREEN COMPACT, PRODUCTION METHOD FOR GREEN COMPACT, AND ELECTROMAGNETIC WAVE ABSORBER
SUBSTITUTED ε-IRON OXIDE MAGNETIC PARTICLE POWDER, PRODUCTION METHOD FOR SUBSTITUTED ε-IRON OXIDE MAGNETIC PARTICLE POWDER, GREEN COMPACT, PRODUCTION METHOD FOR GREEN COMPACT, AND ELECTROMAGNETIC WAVE ABSORBER
[Problem] To provide: a substituted ε-iron oxide magnetic particle powder that has another metal element substituted at a portion of the Fe sites of ε-Fe2O3 and contains a reduced amount of non-magnetic α-type iron oxide; and a production method for the substituted ε-iron oxide magnetic particle powder. [Solution] A substituted ε-iron oxide magnetic particle powder that contains a reduced amount of α-type iron oxide and is produced by neutralizing an acidic aqueous solution that includes trivalent iron ions and ions of a metal that is to substitute a portion of Fe sites to a pH of 2.0–7.0, adding a silicon compound that has a hydrolyzable group to a resultant dispersion that includes either iron oxyhydroxide that includes the substituent metal element or a mixture of iron oxyhydroxide and a hydroxide of the substituent metal element, neutralizing the dispersion to a pH of at least 8.0 before letting the dispersion age, and then coating the iron oxyhydroxide that includes the substituent metal element or the mixture of iron oxyhyrdoxide and a hydroxide of the substituent metal element with a chemical reaction product of the silicon compound and heating.
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机译:[问题]提供:一种在另一种金属元素上取代了ε-Fe 2 Sub> O 3 Sub>和包含减少量的非磁性α型氧化铁;取代的ε-氧化铁磁性粒子粉末的制造方法。 [解决方案]通过中和包含三价铁离子和替代部分Fe的金属离子的酸性水溶液来制备含有减少量的α-型氧化铁的取代ε-氧化铁磁性颗粒粉末。在pH值为2.0-7.0的条件下,将具有可水解基团的硅化合物添加到所得的分散体中,该分散体既包括含有取代金属元素的羟基氧化铁,也包括含有羟基氧化铁和取代基金属元素的氢氧化物的混合物,在分散液老化之前将其分散液的pH值至少为8.0,然后用硅化合物的化学反应产物包被包含取代金属元素或羟基氧化铁和取代金属元素的氢氧化物的混合物的氢氧化铁。加热。
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