A new material MIT-1 comprised of delaminated MWW zeolite nanosheets is made in a one-pot synthesis using a rationally designed organic structure-directing agent (OSDA). The OSDA consists of a hydrophilic head segment that resembles the OSDA used to synthesize the zeolite precursor MCM-22(P), a hydrophobic tail segment that resembles the swelling agent used to swell MCM-22(P), and a di-quaternary ammonium linker that connects both segments. MIT-1 features high crystallinity and surface areas exceeding 500 m[superscript 2] g[superscript −1], and can be synthesized over a wide synthesis window that includes Si/Al ratios ranging from 13 to 67. Characterization data reveal high mesoporosity and acid strength with no detectable amorphous silica phases. Compared to MCM-22 and MCM-56, MIT-1 shows a three-fold increase in catalytic activity for the Friedel–Crafts alkylation of benzene with benzyl alcohol.
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机译:使用合理设计的有机结构导向剂(OSDA),通过一锅法合成制得了由分层的MWW沸石纳米片组成的新材料MIT-1。 OSDA由类似于用于合成沸石前体MCM-22(P)的OSDA的亲水头段,类似于用于使MCM-22(P)溶胀的溶胀剂的疏水尾段和二季铵组成。连接两个段的链接器。 MIT-1具有高结晶度和超过500 m [上标2] g [上标-1]的表面积,可以在宽的合成窗口中合成,包括13/67的Si / Al比。表征数据显示出较高的介孔率和酸强度,无可检测的无定形二氧化硅相。与MCM-22和MCM-56相比,MIT-1对苯与苯甲醇的Friedel-Crafts烷基化反应的催化活性提高了三倍。
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