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Softening and Yielding of Soft Glassy Materials

机译:软质玻璃材料的软化和屈服

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摘要

Solids deform and fluids flow, but soft glassy materials, such as emulsions,foams, suspensions, and pastes, exhibit an intricate mix of solid andliquid-like behavior. While much progress has been made to understand theirelastic (small strain) and flow (infinite strain) properties, suchunderstanding is lacking for the softening and yielding phenomena that connectthese asymptotic regimes. Here we present a comprehensive framework forsoftening and yielding of soft glassy materials, based on extensive numericalsimulations of oscillatory rheological tests, and show that two distinctscenarios unfold depending on the material's packing density. For densesystems, there is a single, pressure-independent strain where the elasticmodulus drops and the particle motion becomes diffusive. In contrast, forweakly jammed systems, a two-step process arises: at an intermediate softeningstrain, the elastic and loss moduli both drop down and then reach a new plateauvalue, whereas the particle motion becomes diffusive at the distinctly largeryield strain. We show that softening is associated with an extensive number ofmicroscopic contact changes leading to a non-analytic rheological signature.Moreover, the scaling of the softening strain with pressure suggest theexistence of a novel pressure scale above which softening and yieldingcoincide, and we verify the existence of this crossover scale numerically. Ourfindings thus evidence the existence of two distinct classes of soft glassymaterials -- jamming dominated and dense -- and show how these can bedistinguished by their rheological fingerprint.
机译:固体会变形,流体会流动,但是柔软的玻璃质材料(如乳液,泡沫,悬浮液和糊剂)会表现出复杂的固液状混合特性。尽管在理解弹性(小应变)和流动(无限应变)特性方面已经取得了很大进展,但是对于将这些渐近状态联系起来的软化和屈服现象仍缺乏这种理解。在此,我们基于振动流变学测试的大量数值模拟,提出了软玻璃材料的软化和屈服的综合框架,并显示了两种不同的情况,这取决于材料的堆积密度。对于密集系统,存在一个与压力无关的单一应变,其中弹性模量下降,粒子运动变得扩散。相反,在弱卡死的系统中,出现了两步过程:在中间软化应变下,弹性模量和损耗模量均下降,然后达到新的平稳值,而在明显更大的屈服应变下,粒子运动变得扩散。我们发现软化与大量微观接触变化相关,从而导致非分析性的流变学特征。此外,软化应变随压力的变化表明存在新的压力标度,高于该压力标度软化并产生巧合,并且我们验证了存在数字上的交叉比例。因此,我们的发现证明了存在两种截然不同的软质玻璃质材料-占主导地位的和密集的-并表明如何通过其流变学指纹来区分它们。

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