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Effect of introduction of furfural on asphalt binder ageing characteristics

机译:引入糠醛对沥青结合料老化特性的影响

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摘要

Asphalt oxidative ageing and excessive hardening are known causes of premature pavementcracking. Asphalt ageing occurs mainly due to the oxidation of certain functional groups inasphalt as well as the loss of the maltene phase disturbing colloidal stability and increasingmicellisation concentration. This in turn can cause large non-soluble asphaltene aggregateswhich are typically suspended in the maltene solution and are stabilised by resin molecules toflocculate. Flocculation can cause the asphalt to become stiffer and more brittle. It should benoted that excessive hardening and brittleness of asphalt caused by oxidation during pavementproduction and service life increase the susceptibility of asphalt pavements to cracking. Therefore,reducing the extent of asphalt oxidation could increase pavement service life. Therefore,it is imperative to reduce/delay asphalt oxidation in asphalt binder. There have been severalstudies on delaying asphalt oxidation by introducing modifiers and anti-ageing additives. Furfural,an organic compound derived from a variety of agricultural by-products, has been shownto be a promising modifier for petroleum asphalt binders used in asphalt pavement. Accordingly,this paper investigates the effect of introducing furfural as an antioxidant for asphalt byevaluating the extent of oxidation ageing in asphalt specimens modified by 1%, 2% and 5%furfural. To do so, furfural was introduced to asphalt and the level of change in physiochemicaland rheological properties of asphalt after specimens were exposed to short- and long-termageing was examined. Accordingly, performance characteristics of the base asphalt were comparedwith those of furfural-modified asphalts using a rotational viscometer, Fourier transforminfrared spectroscopy and a dynamic shear rheometer to evaluate the rheological properties ofasphalt modified with furfural at different percentages. The study results showed that the additionof furfural helped reduce the extent of oxidative ageing while enhancing high-temperatureperformance of asphalt binder. Specifically, it was found that the 2% furfural modification hadthe lowest ageing index after ageing, indicating an improvement in binder oxidative ageing
机译:沥青氧化老化和过度硬化是已知的过早路面开裂的原因。沥青老化的发生主要是由于沥青中某些官能团的氧化以及麦芽相的损失,从而破坏了胶体的稳定性和胶束浓度的增加。反过来,这会导致大的不溶性沥青质聚集体,这些聚集体通常悬浮在麦芽溶液中,并通过树脂分子的絮凝而稳定。絮凝会导致沥青变得更硬,更脆。应当指出的是,在路面生产和使用寿命期间由于氧化而引起的沥青的过度硬化和脆性增加了沥青路面开裂的敏感性。因此,减少沥青的氧化程度可以延长路面使用寿命。因此,必须减少/延迟沥青结合料中的沥青氧化。关于通过引入改性剂和抗老化添加剂来延迟沥青氧化的研究已有很多。糠醛是一种衍生自多种农业副产品的有机化合物,已被证明是用于沥青路面的石油沥青粘合剂的有前途的改性剂。因此,本文通过评估经1%,2%和5%糠醛改性的沥青样品的氧化老化程度,研究了引入糠醛作为沥青的抗氧化剂的效果。为此,将糠醛引入沥青中,并检查了标本短期和长期暴露后沥青的理化和流变特性的变化水平。因此,使用旋转粘度计,傅立叶变换红外光谱和动态剪切流变仪将基础沥青的性能与糠醛改性沥青的性能进行了比较,以评估不同比例糠醛改性沥青的流变性能。研究结果表明,糠醛的添加有助于减少氧化老化的程度,同时提高了沥青粘合剂的高温性能。具体而言,发现老化后2%的糠醛改性具有最低的老化指数,表明粘合剂氧化老化的改善。

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