During extrusion-cooking of starchy products, the molten material is forced through a die so that the sudden pressure drop causes part of the water to vaporize giving an expanded, porous structure. The moisture is lost due to evaporation and heat transfers, as the material cools down. Thus the material crosses glass transition and becomes solid. No deterministic model is available to describe satisfactory dynamic, multiphysic and multiphase phenomena during expansion. Current models are too complex to be coupled with Ludovic (software for simulation of co-rotating twin-screw extrusion process), in order to predict the cellular structure of the starchy foams.The objective of this work is to elaborate phenomenological model of expansion and couple it with Ludovic mechanistic model. This model of bubble growth in a viscoelastic biopolymer matrix in the transition state from rubbery to solid phase takes also into account bubbles nucleation, coalescence, setting and shrinkage. The input variables are the shear viscosity η, temperature T and moisture content MC at the die exit, computed by Ludovic , and the material storage moduli E’( T>Tg), available from litterature 1,2. The output variables are the macrostructural and cellular structural features of starchy foams. The macrostructure is described by bulk expansion indices (density, anisotropy). The mean cell size, mean cell wall thickness and cell fineness, defining the cellular structure, are determined by Xray tomography (ESRF). Starting from experimental results obtained in a large range of thermo-mechanical conditions, a conceptual map of influence relationships between these variables has been built and a general mathematical expression of the model is suggested: VEI = K. (η/η0)^n in which K and n depend on T, MC and E’ whereas VEI is the volumetric expansion index of the extruded material, for instance. Predicted data are then compared to experimental ones
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机译:在淀粉产品的挤压蒸煮过程中,熔融材料被迫通过模具,因此突然的压降导致部分水汽化,从而形成膨胀的多孔结构。随着材料的冷却,水分由于蒸发和热传递而损失。因此,该材料穿过玻璃化转变并变成固体。没有确定性模型可用来描述扩展过程中令人满意的动态,多物理和多相现象。当前模型太复杂,无法与Ludovic(用于同向旋转双螺杆挤出过程的模拟软件)结合使用,以预测淀粉状泡沫的孔结构。这项工作的目的是阐述膨胀和膨胀的现象学模型。与Ludovic机械模型结合使用。在从橡胶态到固相的过渡状态下,粘弹性生物聚合物基质中气泡的生长模型也考虑了气泡成核,聚结,凝结和收缩。输入变量是由Ludovic计算的模头出口处的剪切粘度η,温度T和水分含量MC以及可从文献1,2获得的材料存储模量E′(T> Tg)。输出变量是淀粉泡沫的宏观结构和孔结构特征。宏观结构由体积膨胀指数(密度,各向异性)描述。定义细胞结构的平均细胞大小,平均细胞壁厚度和细胞细度通过X射线断层扫描(ESRF)确定。从在大范围热机械条件下获得的实验结果开始,已建立了这些变量之间的影响关系的概念图,并提出了该模型的一般数学表达式:VEI = K.(η/η0)^ n in其中K和n取决于T,MC和E',而VEI例如是挤压材料的体积膨胀指数。然后将预测数据与实验数据进行比较
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