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Rotational-Vibrational Raman Spectroscopy for Measurements of Thermochemistry in Non-isobaric Environments

机译:旋转振动拉曼光谱法在非等压环境中的热化学测量

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摘要

The present work examines line measurements of pressure, temperature, anddensity in high speed, non-isobaric flows emanating from an underexpanded jet nozzle.Line images of rotational and vibrational Raman spectra are collected for a 8-mmlinear laser probe, and are combined onto the same EMCCD detector. Combiningthe two techniques allows for a single-shot measurement of major species, pressure,and temperature in a turbulent non-isobaric environment that is chemically reacting.Temperature measurements along the laser test section are extracted from the rotationalRaman spectrum, whereas major species densities are measured by examiningthe intensities of their respective vibrational Raman lines. Pressure can be calculatedusing an equation of state, in every location along the linear laser probe. The techniquefeasibility is examined by performing measurements of pressure, temperatureand density in a non-reacting underexpanded air jet where the chemical compositionis constant and known. Future work will extend the technique to chemically reactingsupersonic flows with unknown chemical composition.
机译:本工作研究了从膨胀不足的喷嘴喷出的高速,非等压流中的压力,温度和密度的线测量结果,收集了8毫米线性激光探针的旋转和振动拉曼光谱的线图像,并将其组合到相同的EMCCD检测器。结合这两种技术,可以在发生化学反应的湍流非等压环境中一次性测量主要物质,压力和温度。从旋转拉曼光谱中提取沿激光测试部分的温度测量值,同时测量主要物质密度通过检查它们各自的拉曼振动线的强度。可以使用状态方程在线性激光探针的每个位置上计算压力。通过在化学成分恒定且已知的非反应性欠膨胀空气喷嘴中进行压力,温度和密度的测量,可以检验该技术的可行性。未来的工作将把该技术扩展到化学成分未知的超音速流化学反应。

著录项

  • 作者

    Bayeh Alexander C.;

  • 作者单位
  • 年度 2010
  • 总页数
  • 原文格式 PDF
  • 正文语种 en_US
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